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KMnO(4)underset(R.A.)overset(H^(+))toMn^...

`KMnO_(4)underset(R.A.)overset(H^(+))toMn^(x)`
`KMnO_(4)underset(R.A.)overset(OH^-)toMn^(y)`
`x+y`

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To solve the problem, we need to determine the oxidation states of manganese (Mn) in two different reactions involving potassium permanganate (KMnO₄) in acidic and basic media. ### Step-by-Step Solution: 1. **Identify the Reaction in Acidic Medium:** - The reaction is given as: \[ KMnO_4 \xrightarrow{R.A.} Mn^{(x)} \] - In acidic medium, KMnO₄ is reduced to MnO₂. 2. **Determine the Oxidation State of Mn in MnO₂:** - The formula for MnO₂ can be expressed as: \[ x + 2(-2) = 0 \] - Solving for \(x\): \[ x - 4 = 0 \implies x = +4 \] 3. **Identify the Reaction in Basic Medium:** - The reaction is given as: \[ KMnO_4 \xrightarrow{OH^-} Mn^{(y)} \] - In basic medium, KMnO₄ is reduced to MnO₄²⁻. 4. **Determine the Oxidation State of Mn in MnO₄²⁻:** - The formula for MnO₄²⁻ can be expressed as: \[ y + 4(-2) = -2 \] - Solving for \(y\): \[ y - 8 = -2 \implies y = +6 \] 5. **Calculate \(x + y\):** - Now that we have both oxidation states: \[ x = +4 \quad \text{and} \quad y = +6 \] - Therefore, \[ x + y = 4 + 6 = 10 \] ### Final Answer: \[ x + y = 10 \]
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Volumetric titrations involving KMnO_(4) , are carried out only in presence of dilute H_(2)SO_(4) but not in the presence of HCI or HNO_(3) This is because oxygen produced from KMnO_(4) + dil: H_(2)SO_(4) , is used only for oxidizing the reducing agent. Moreover, H2SO4 does not give any oxygen of its own to oxidize the reducing agent. In case HCI is used, the oxygen produced from KMnO_(4) + HCI is partly used up to oxidize HCI and in case HNO_(3) is used, it itself acts as oxidizing agent and partly oxidizes the reducing agent. KMnO_(4) , in various mediums gives following products Mn^(7+)overset(H^(+))toMn^(2+) Mn^(7+)overset(H_(2)O)toMn^(4+) Mn^(7+)underset(OH^(-))toMn^(6+) Q MnO_(4)^(2-) (1 mole) in neutral medium disproportionates to,

Volumetric titrations involving KMnO_(4) , are carried out only in presence of dilute H_(2)SO_(4) but not in the presence of HCI or HNO_(3) This is because oxygen produced from KMnO_(4) + dil: H_(2)SO_(4) , is used only for oxidizing the reducing agent. Moreover, H2SO4 does not give any oxygen of its own to oxidize the reducing agent. In case HCI is used, the oxygen produced from KMnO_(4) + HCI is partly used up to oxidize HCI and in case HNO_(3) is used, it itself acts as oxidizing agent and partly oxidizes the reducing agent. KMnO_(4) , in various mediums gives following products Mn^(7+)overset(H^(+))toMn^(2+) Mn^(7+)overset(H_(2)O)toMn^(4+) Mn^(7+)underset(OH^(-))toMn^(6+) QThe number of moles of KMnO_(4) that will be needed to react with one mole of sulphite in an acidic solution is

Volumetric titrations involving KMnO_(4) , are carried out only in presence of dilute H_(2)SO_(4) but not in the presence of HCI or HNO_(3) This is because oxygen produced from KMnO_(4) + dil: H_(2)SO_(4) , is used only for oxidizing the reducing agent. Moreover, H2SO4 does not give any oxygen of its own to oxidize the reducing agent. In case HCI is used, the oxygen produced from KMnO_(4) + HCI is partly used up to oxidize HCI and in case HNO_(3) is used, it itself acts as oxidizing agent and partly oxidizes the reducing agent. KMnO_(4) , in various mediums gives following products Mn^(7+)overset(H^(+))toMn^(2+) Mn^(7+)overset(H_(2)O)toMn^(4+) Mn^(7+)underset(OH^(-))toMn^(6+) QThe equivalent weight of KMnO_(4) , in the given reaction is KMnO_(4)toK_(2)MnO_(4)+ MnO_(2) + O_(2)

Volumetric titrations involving KMnO_(4) , are carried out only in presence of dilute H_(2)SO_(4) but not in the presence of HCI or HNO_(3) This is because oxygen produced from KMnO_(4) + dil: H_(2)SO_(4) , is used only for oxidizing the reducing agent. Moreover, H2SO4 does not give any oxygen of its own to oxidize the reducing agent. In case HCI is used, the oxygen produced from KMnO_(4) + HCI is partly used up to oxidize HCI and in case HNO_(3) is used, it itself acts as oxidizing agent and partly oxidizes the reducing agent. KMnO_(4) , in various mediums gives following products Mn^(7+)overset(H^(+))toMn^(2+) Mn^(7+)overset(H_(2)O)toMn^(4+) Mn^(7+)underset(OH^(-))toMn^(6+) QNumber of electrons transferred in each case when KMnO_(4) acts as an oxidizing agent to give MnO_(2) , Mn^(++) Mn(OH)_(3) , and MnO_(4)^(2-) are respectively

Choose the correct code by identifying (X), (Y) and (Z) in each case for the changes indicated: (i) CrO_(2)Cl_(2) overset(KOH) to (X) overset(conc." "H_(2)SO_(4))to(Y) overset(AgNO_(3))to(Z) (ii) CrCl_(3)(aq) underset(NaOH)overset("excess")to (X) underset(H_(2)O," boil")overset(Na_(2)O_(2))to (Y) underset("acetate")overset("lead")to (Z) (iii) ZnSO_(4)(aq) overset(Na_(2)CO_(3))to (X) overset(Delta)to (Y) underset("nitrate, "Delta)overset("cobalt")to(Z) (iv) CuCl_(2)(aq) underset(H_(2)S)overset(NH_(4)OH)to (X) underset(Delta)overset(HNO_(3))to (Y) underset("excess")overset(KCN)to(Z)

Which of the following is correct representatin of the reaction when BF_(3) reacts with ammonia? (i) F - underset(F)underset(|)overset(F)overset(|)(B) + underset(H)underset(|)overset(H)overset(|)( :N) - H to [F - underset(F)underset(|)overset(F)overset(|)(B) to underset(H)underset(|)overset(H)overset(|)( :N) - H] (ii) F - underset(F)underset(|)overset(F)overset(|)(B) + underset(H)underset(|)overset(H)overset(|)( :N) - H to [F - underset(F)underset(|)overset(F)overset(|)(B) to underset(H)underset(|)overset(H)overset(|)(N) - H]

In the series, C_2H_2 underset(2.0 eq.)overset(NaNH_2)to X underset(2.0 eq.)overset(CH_3 I)to Y underset(H_2 SO_4 ,H_2O )overset(Hg SO_4)to Z the compound Z is :

RESONANCE ENGLISH-D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS -Exercise 2
  1. A black mineral (A) on heating in presence of air gives a gas (B). (A)...

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  2. What happens when a solution of potassium iodide is added to a solutio...

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  3. KMnO(4)underset(R.A.)overset(H^(+))toMn^(x) KMnO(4)underset(R.A.)ove...

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  4. The no. of electrons satisfying n+l=7 for Lu (atomic number:71)

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  5. Correct statements about transition metals are that they:

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  6. Transition elements have greater tendency to form complexes because

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  7. Titanium dioxide is added in the interior paints for walls of rooms, h...

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  8. The melting point of Zn is lower as compared to those of the other ele...

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  9. The less stable oxidation state of Cr are:

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  10. Which of the following statement is/are correct?

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  11. Select correct statement(s).

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  12. The colour of the transition metal ions is/are due to:

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  13. Which of the following chemical reaction(s) is/are involved in develop...

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  14. Which of the following statement are correct when a mixture of NaCl a...

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  15. Monazite is the ore of:

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  16. Pyrolusite is used to prepare potassium permanganate MnO(2)overset(X)t...

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  17. Which is not a mineral of aluminium?

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  18. Transition metals usually from coloured complexes and d-d transitions ...

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  19. Transition metals usually from coloured complexes and d-d transitions ...

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  20. Name the compound which gives blue colour to the glass.

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