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When XO(2) is fused with an alkali metal...

When `XO_(2)` is fused with an alkali metal hydroxide in presence of an oxidizing agent such as `KNO_(3)`, a dark green product is formed which disproportionates in acidic solution to give a dark purple solution. X is:

A

Mn

B

Cr

C

V

D

Ti

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The correct Answer is:
To solve the question, we need to identify the element 'X' in the compound `XO2` based on the given reactions and products formed. Here’s a step-by-step breakdown of the solution: ### Step 1: Understanding the Reaction The question states that when `XO2` is fused with an alkali metal hydroxide (like KOH) in the presence of an oxidizing agent (like KNO3), a dark green product is formed. ### Step 2: Identifying the Dark Green Product The dark green product formed in the reaction is likely to be a manganese compound, specifically `K2MnO4`. This is known to be formed when manganese dioxide (`MnO2`) reacts with potassium hydroxide in the presence of an oxidizing agent. ### Step 3: Disproportionation Reaction The question mentions that this dark green product disproportionates in an acidic solution to yield a dark purple solution. The dark purple solution is identified as potassium permanganate (`KMnO4`), which is a well-known compound. ### Step 4: Writing the Balanced Equation The balanced equation for the disproportionation of `K2MnO4` in acidic solution can be written as: \[ K2MnO4 + 4H^+ \rightarrow 2KMnO4 + MnO2 + 2H2O \] ### Step 5: Conclusion From the above steps, we can conclude that the element 'X' in the compound `XO2` is manganese (Mn). The other options (chromium, vanadium, and titanium) do not yield the same products under the given conditions. ### Final Answer Thus, the answer is: **X is Manganese (Mn).** ---
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RESONANCE ENGLISH-D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS -Exercise 3
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  4. Match the catalysts to the correct processes :

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  5. The colour of KMnO(4) is due to : [where M to metal, L to ligand]

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  6. A compound of vanadium chloride has spin only magnetic moment of 1.73 ...

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  7. Which one of the following exhibits the largest number of oxidation st...

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  8. Copper becomes green when exposed to moist air for long period. This i...

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  9. Which of the following statements is false?

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  10. Which one of the following species is stable in aqueous solution?

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  11. The transition metal ions responsible for colour in ruby and emerald a...

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  12. The pair of compounds having metals in their highest oxidation state i...

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  13. When XO(2) is fused with an alkali metal hydroxide in presence of an o...

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  14. The highest value of the calculated spin-only magnetic moment (in BM)...

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  15. The transition element that has lowest enthalpy of atomisation, is :

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  16. The 71^(st) electron of an element X with an atomic number of 71 enter...

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  17. The element that usually does NOT show variable oxidation states is :

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  18. underline (A) overset( 4 K OH, O(2))to 2underline (B) underset(("Green...

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  20. The correct order of atomic radii in group 13 elements is

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