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Which of the following weighs less when ...

Which of the following weighs less when weighed in magnetic field?

A

`ScCl_(3)`

B

`FeCl_(3)`

C

`TiCl_(3)`

D

`VCl_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "Which of the following weighs less when weighed in a magnetic field?", we need to identify the magnetic properties of the given compounds. The key points to remember are: 1. **Diamagnetic substances**: These substances have all their electrons paired and are repelled by a magnetic field, resulting in a decrease in weight when weighed in such a field. 2. **Paramagnetic substances**: These have unpaired electrons and are attracted to a magnetic field, hence they do not weigh less. Now, let's analyze the given compounds step by step: ### Step 1: Analyze SeCl3 (Selenium trichloride) - **Oxidation state of Selenium (Se)**: In SeCl3, Se is in the +3 oxidation state. - **Electronic configuration**: The electronic configuration of Se in this state is Argon (Ar), 3d^0, 4s^0. - **Unpaired electrons**: There are no unpaired electrons in this configuration. - **Conclusion**: Since SeCl3 is diamagnetic, it will weigh less in a magnetic field. ### Step 2: Analyze FeCl3 (Iron(III) chloride) - **Oxidation state of Iron (Fe)**: In FeCl3, Fe is in the +3 oxidation state. - **Electronic configuration**: The electronic configuration of Fe in this state is Argon (Ar), 3d^5, 4s^0. - **Unpaired electrons**: There are five unpaired electrons in the 3d subshell. - **Conclusion**: Since FeCl3 is paramagnetic, it will not weigh less in a magnetic field. ### Step 3: Analyze TiCl3 (Titanium(III) chloride) - **Oxidation state of Titanium (Ti)**: In TiCl3, Ti is in the +3 oxidation state. - **Electronic configuration**: The electronic configuration of Ti in this state is Argon (Ar), 3d^1, 4s^0. - **Unpaired electrons**: There is one unpaired electron in the 3d subshell. - **Conclusion**: Since TiCl3 is paramagnetic, it will not weigh less in a magnetic field. ### Step 4: Analyze VCl3 (Vanadium(III) chloride) - **Oxidation state of Vanadium (V)**: In VCl3, V is in the +3 oxidation state. - **Electronic configuration**: The electronic configuration of V in this state is Argon (Ar), 3d^2, 4s^0. - **Unpaired electrons**: There are two unpaired electrons in the 3d subshell. - **Conclusion**: Since VCl3 is paramagnetic, it will not weigh less in a magnetic field. ### Final Conclusion After analyzing all the compounds, we find that: - **SeCl3** is the only compound that is diamagnetic and will weigh less in a magnetic field. ### Answer: SeCl3 weighs less when weighed in a magnetic field. ---
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