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Cuprous chloride can not be prepared :...

Cuprous chloride can not be prepared :

A

by passing `SO_(2)` through the solution containing `CuSO_(4) and NaCl`

B

by heating excess of copper with concentrated HCl in presence of a little `KClO_(3)`

C

by boiling copper sulphate solution with excess of copper turnings in presence of hydrochloric acid.

D

by dissolving cupric oxide or coper carbonate in concentrated HCl.

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

(A) `2CuSO_(4)+2NaCl+2H_(2)O+SO_(2)toCu_(2)Cl_(2)+Na_(2)SO_(4)+2H_(2)SO_(4)`
(B) `Cu+HCl+[O]toCuCl_(2)+H_(2)O,CuCl_(2)+CutoCu_(2)Cl_(2)`
(C) `CuSO_(4)+2HCl" "CuCl_(2)+H_(2)SO,CuCl_(2)+CutoCu_(2)Cl_(2)`
(D) `CuO+2HCl to CuCl_(2)+H_(2)O,CuCl_(2)` is not formed.
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