Home
Class 11
CHEMISTRY
The major product (H) in the given react...

The major product (H) in the given reaction sequence is :
`CH_3-CH_2-CO-CH_3overset(HCN)to Gunderset("Heat")overset(95% H_2SO_4)toH`

A

`CH_3-CH=undersetunderset(CH_3)(|)C-COOH`

B

`CH_3-CH=undersetunderset(CH_3)(|)C-CN`

C

`CH_3-CH_2-undersetunderset(CH_3)(|)oversetoverset(OH)(|)C-COOH`

D

`CH_3-CH=undersetunderset(CH_3)(|)C-CO-NH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the reaction sequence step by step. ### Step 1: Identify the starting material The starting material is **CH₃-CH₂-CO-CH₃** (butan-2-one). ### Step 2: Reaction with HCN When butan-2-one is treated with HCN (hydrogen cyanide), it undergoes a nucleophilic addition reaction. The carbonyl carbon of the ketone is electrophilic and reacts with the nucleophilic cyanide ion (CN⁻) from HCN. This results in the formation of a cyanohydrin. **Product G:** The product formed is **CH₃-CH₂-C(OH)(CN)-CH₃** (2-hydroxy-2-methylbutanenitrile). ### Step 3: Treatment with 95% H₂SO₄ Next, the cyanohydrin (Product G) is treated with concentrated sulfuric acid (95% H₂SO₄). This step involves hydrolysis of the nitrile group (CN) to form a carboxylic acid (COOH). During this reaction, the cyanide group is converted to a carboxylic acid, and the hydroxyl group remains intact. **Intermediate Product:** The resulting product after hydrolysis is **CH₃-CH₂-C(OH)-COOH** (2-hydroxybutanoic acid). ### Step 4: Heating the product Upon heating, dehydration occurs. The hydroxyl group (OH) and a hydrogen atom from the adjacent carbon can be eliminated, leading to the formation of a double bond (alkene). This results in the formation of an unsaturated carboxylic acid. **Final Product H:** The final product after dehydration is **CH₃-CH₂-C=CH-COOH** (butenoic acid). ### Conclusion The major product (H) in the given reaction sequence is **CH₃-CH₂-C=CH-COOH**. ---
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-3 Part-2 JEE (MAIN ) OFFLINE PROBLEMS|10 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-3 Part-2 JEE (MAIN ) ONLINE PROBLEMS|10 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-2 Part-4|8 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise APSP Part - 3|22 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos

Similar Questions

Explore conceptually related problems

The major product H of the given reaction sequence is CH_(3) - CH_(2) CO - CH_(3) overset (Theta_(CN)) to G - overset (95% H_(2) SO_(4)) underset (Heat) to H

The major product formed in the following reaction is : CH_3CH = CHCH(CH_3)_2 overset(HBr)(to)

The major product (Y)in the following reaction sequency is : CH_(3) - overset( CH_(3))overset(|)(C)H - CH= CH_(2) overset( Br_(2) //H_(2)O)(rarr) X overset("conc."H_(2)SO_(4)//Delta)(rarr)Y

Product formed in the following reaction is CH_3CH_2CH(OH)CH_3overset(H_2SO_4)rarr

The major product of the following reaction is : CH_(3)CH=CHCO_(2)CH_(3)overset(LiAlH_(4))rarr

What will be the final product in the following reaction sequence? CH_3CH_2CN overset(H^(+)//H_2O)to A underset(Delta)overset(NH_3)to B overset(NaOBr)to C

Product of the given reaction CH_3CH_2-CH=CH_3overset(SiO_2)rarr will be

The major product [B] in the following reaction is : CH_(3)-CH_(3)-overset(CH)overset("| ")"CH"-CH_(2)-OCH_(2)-CH_(3)overset(HI)underset("Heat")rarr [A]" alcohol"overset(H_(2)SO_(4))underset(Delta)rarr [B]

RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-Exercise-3 Part-1
  1. Identify (X),(Y) and (Z) in the following synthetic scheme and write t...

    Text Solution

    |

  2. Identify the set of reagents/ reaction condition ‘X’ and ‘Y’ in the fo...

    Text Solution

    |

  3. How many structures of F is possible?

    Text Solution

    |

  4. Which of the reagents on reaction with cyclohexanol gives best yield o...

    Text Solution

    |

  5. Match the following (one term in column-I may match with more than one...

    Text Solution

    |

  6. In the following reaction sequence , product I,J and L are formed , K ...

    Text Solution

    |

  7. In the following sequence, product I, ,J and L are formed. K represent...

    Text Solution

    |

  8. In the following sequence, product I,J and L are formedK represents a ...

    Text Solution

    |

  9. The total number of alkenes possible by dehydrobromination of 3-bromo-...

    Text Solution

    |

  10. An acyclic hydrocarbon P, having molecular fromula C(6)H(10) gave acet...

    Text Solution

    |

  11. An acyclic hydrocarbon P, having molecular formula C6H10 , gave aceton...

    Text Solution

    |

  12. The major product (H) in the given reaction sequence is : CH3-CH2-CO...

    Text Solution

    |

  13. Match the chemical conversion in List-I with the approprotae reagents ...

    Text Solution

    |

  14. In the following reactions : Compound X is

    Text Solution

    |

  15. In the following reactoins The major compound Y is

    Text Solution

    |

  16. The number of hydroxyl group(s) in Q is overset(H^(+))underset("hea...

    Text Solution

    |

  17. The desired product X can be prepared by reacting the major product of...

    Text Solution

    |

  18. LIST-I contains reactions and LIST-II contains major products.

    Text Solution

    |