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The reaction, Ph-CH(2)-CH=CH-overset(OH)...

The reaction, `Ph-CH_(2)-CH=CH-overset(OH)overset(|)(CH)-CH_(3) underset("ketone(excess)"//Delta)overset(Al(BuO)_(3))rarrPhCH_(3)CH=CH-overset(O)overset(||)(C)-CH_(3)` is known as :

A

Wolff-kishner reduction

B

Oppenauer oxidation

C

Meerwein - Ponndorf reaction

D

Clemmensen reduction

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The correct Answer is:
To determine the name of the reaction given in the question, we will analyze the components and transformations involved in the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: - The reactants are `Ph-CH2-CH=CH-CH(CH3)-OH` (an alcohol) and an excess of ketone in the presence of `Al(BuO)3`. - The product is `Ph-CH3-CH=CH-CO-CH3` (a ketone). 2. **Determine the Type of Reaction**: - The reaction involves the conversion of an alcohol to a ketone, which indicates that it is an oxidation reaction. In this case, the hydroxyl group (-OH) is being oxidized to a carbonyl group (C=O). 3. **Evaluate the Options**: - The options provided are: - Wolf-Kishner Reduction - Clemenson Reduction - Marwin Reaction - Open Air Oxidation - Since we established that the reaction is an oxidation, we can eliminate the reduction reactions (Wolf-Kishner, Clemenson, and Marwin). 4. **Identify the Correct Reaction**: - The only option left that corresponds to an oxidation reaction is "Open Air Oxidation." This is a known reaction where alcohols are oxidized to ketones or aldehydes in the presence of oxidizing agents. 5. **Conclusion**: - Therefore, the correct answer to the question is that the reaction is known as **Open Air Oxidation**.

To determine the name of the reaction given in the question, we will analyze the components and transformations involved in the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: - The reactants are `Ph-CH2-CH=CH-CH(CH3)-OH` (an alcohol) and an excess of ketone in the presence of `Al(BuO)3`. - The product is `Ph-CH3-CH=CH-CO-CH3` (a ketone). ...
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CH_3-overset(OH)overset(|)(CH)-overset(O)overset(||)(C )-CH_2 - CH_(3) will respond to

The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

The acidic strength of the given compounds follows the order I. CH_(3)-CH=CH-overset(O)overset(||)C-OH II. CH_(3)-overset(..)underset(..)O-CH=CH-overset(O)overset(||)C-OH III. CH_(3)-CH_(2)-overset(O)overset(||)C-OH

Which of the following is the correct ease of dehydration ? I CH_(3) - CH_(2)-CH_(2)-underset(OH)underset(|)(CH_(2)) , II CH_(3)-CH_(2)-overset(OH)overset(|)(CH)-CH_(3) , III CH_(2) = CH -overset(OH)overset(|)(CH)-CH_(3) , IV

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