Home
Class 11
CHEMISTRY
The reaction, R(2)CO+4[H] underset("Conc...

The reaction, `R_(2)CO+4[H] underset("Conc. HCl")overset("Zn-Hg")rarr R_(2)CH_(2)+H_(2)O` is well known as :

A

Wurtz reaction

B

Rsoenmund reduction

C

Kolbe reaction

D

Clemmensen reduction

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction \( R_2CO + 4[H] \) in the presence of concentrated HCl and Zn-Hg, we need to identify the name of the reaction. Here’s a step-by-step breakdown: ### Step 1: Identify the Reactants and Products The reaction involves a carbonyl compound \( R_2CO \) (which can be a ketone) and hydrogen in the presence of concentrated hydrochloric acid (HCl) and a zinc-mercury amalgam (Zn-Hg). The products are \( R_2CH_2 \) (an alkane) and water (H2O). ### Step 2: Understand the Role of Reagents - **Concentrated HCl**: Acts as a catalyst in this reaction. - **Zn-Hg (syngamalgam)**: This reagent is known for its reducing properties, particularly in the reduction of carbonyl groups. ### Step 3: Recognize the Type of Reaction This reaction is a reduction reaction where the carbonyl group (C=O) is reduced to a methylene group (C-H) in the presence of the reducing agent (Zn-Hg) and acid (HCl). ### Step 4: Compare with Known Reactions Now, we need to compare this reaction with the options provided: - **Woods Reaction**: Involves the synthesis of higher alkynes from alkyl halides, which does not match. - **Rosenthal Reduction**: Reduces acyl chlorides to aldehydes, which does not match. - **Colb Reaction**: Involves sodium phenoxide and carbon dioxide to produce salicylic acid, which does not match. - **Clemensen Reduction**: Specifically reduces carbonyl compounds (aldehydes and ketones) to alkanes using Zn-Hg in the presence of HCl. ### Step 5: Conclusion Since the given reaction matches the description of the Clemensen reduction, we conclude that the correct answer is: **Answer: D. Clemensen Reduction** ---
Promotional Banner

Topper's Solved these Questions

  • REDUCTION, OXIDATION & HYDROLYSIS REACTIONS

    RESONANCE ENGLISH|Exercise Part-III : High Level Problems (Subjective Questions)|6 Videos
  • REDUCTION, OXIDATION & HYDROLYSIS REACTIONS

    RESONANCE ENGLISH|Exercise Only One Option Correct Type|4 Videos
  • REDUCTION, OXIDATION & HYDROLYSIS REACTIONS

    RESONANCE ENGLISH|Exercise Additional problems for self Practice (Part-1)|30 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos
  • S BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Biomolecules & Polymer)|4 Videos

Similar Questions

Explore conceptually related problems

The reaction R-underset(O)underset(||)C-R underset(H_2SO_4)overset(N_3 H)rarrRCONHR + N_2 is called

In the reaction CH_(3)CN+2H underset("Ether")overset(HCl)(rarr) X overset("Boiling "H_(2)O)(rarr) Y , the term Y is

In the reaction CH_(3)CN+2H underset("Ether")overset(HCl)(rarr) X overset("Boiling "H_(2)O)(rarr) Y , the term Y is

In the reaction CH_(3)CH_(2)CH=CH_(2)underset((2)NaBD_(4))overset((1)Hg(OAc)_(2),H_(2)O)rarr the product obtained is

Complete the following reactions: (i) C_(2)H_(5)I+H_(2) underset(C_(2)H_(5)OH)overset(Zn-Cu)toK (ii) CH_(30COONa+H_(2)O overset("Electrolysis")toY (iii) CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CH_(3) underset(773K)overset(Cr_(2)O_(3)//Al_(2)O_(3))toZ

CH_(3)CH=CH2underset(H^(+))overset(CO+H_(2)O)toCH_(3)-underset(COOH)underset(|)"CH"-CH_(2) is known as:

In the following reaction H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=CH_(2) overset(H_(2)O //H^(o+))(rarr) underset(("Major"),("product"))(A)underset(("Minor"),("product"))(B) The major product is

In the following reaction C is, CH_(3) - CH = CH_(2) + HCl underset("Peroxide")overset("Organic")(rarr) A underset("Moist")overset(Ag2O)(rarr) B overset("Et MgBr")(rarr) C

In the manufacture of sodium carbonate, following reactions are involved: (A) overset(Delta)rarr (B) + CO_(2) (B) +H_(2)O rarr (C ) overset(+NH_(4)Cl rarr (D)overset(+H_(2)O)rarr underset("Solution")(E ) (E )+CO_(2)rarr (F) (F)+NaCl rarr (G) overset("Heat")rarr Na_(2)CO_(3)+CO_(2)+H_(2)O (D) is a gas which is soluble in H_(2)O (A) is

In the manufacture of sodium carbonate, following reactions are involved: (A) overset(Delta)rarr (B) + CO_(2) (B) +H_(2)O rarr (C ) overset(+NH_(4)Cl rarr (D)overset(+H_(2)O)rarr underset("Solution")(E ) (E )+CO_(2)rarr (F) (F)+NaCl rarr (G) overset("Heat")rarr Na_(2)CO_(3)+CO_(2)+H_(2)O (D) is a gas which is soluble in H_(2)O (C ) is

RESONANCE ENGLISH-REDUCTION, OXIDATION & HYDROLYSIS REACTIONS-Part-II : National Standard Examination in Chemistry
  1. If 3- hexanone is reacted with NaBH(4) followed by hydrolysis with D(2...

    Text Solution

    |

  2. Hydrogenation of benzoyl chloride in the presence of Pd on BaSO(4) giv...

    Text Solution

    |

  3. The reaction, R(2)CO+4[H] underset("Conc. HCl")overset("Zn-Hg")rarr R(...

    Text Solution

    |

  4. Acetone will be obtained on ozonolysis of

    Text Solution

    |

  5. Which of the following are reducing agents among the following?

    Text Solution

    |

  6. Reduction of an isonitrile gives a

    Text Solution

    |

  7. Methane may be obtained from monochloromethane by

    Text Solution

    |

  8. The compound which does not react with lithium aluminium hydride is

    Text Solution

    |

  9. The compound which would yield 5- Oxo-2-methylhexanal on reductive ozo...

    Text Solution

    |

  10. Reduction of methylbenzoate (C(6)H(5)COOCH(3)) to benzyl alcohol (C(6)...

    Text Solution

    |

  11. Oxidation of cyclopentanol to cyclopentanone can be accomplished by us...

    Text Solution

    |

  12. Carbonyl compounds can generally be converted to hydrocarbons by

    Text Solution

    |

  13. Which of the following reagents would not be a good choice for reducin...

    Text Solution

    |

  14. Suggest the suitable reagent for the following transformation.

    Text Solution

    |

  15. An isocyanide on reduction with hydrogen in the presence of platinum g...

    Text Solution

    |

  16. Compound X (C(5)H(10)O) is a chiral alcohol. It is catalytically hydro...

    Text Solution

    |

  17. 4-Oxobutanoic acid is reduced with Na-borohydride and the product is t...

    Text Solution

    |

  18. A solution of sodium metal in liquid ammonia is strongly reducing due ...

    Text Solution

    |

  19. Which of the following statements is true for the reaction given below...

    Text Solution

    |

  20. Complete catalytic hydrogenation of napthalene gives decalin (C(10)H(1...

    Text Solution

    |