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X' compound (C(4)H(8)O) decolorises brom...

X' compound `(C_(4)H_(8)O)` decolorises bromine water react with `I_(2)` & NaOH it give yellow ppt identify 'X'

A

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(3)`

B

`CH_(3)-underset(OH)underset(|)(CH)-CH=CH_(2)`

C

`CH_(3)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-CH_(3)`

D

`CH_(3) -HC=CH-underset(OH)underset(|)(CH_(2))`

Text Solution

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The correct Answer is:
To identify the compound X with the molecular formula \( C_4H_8O \), we will follow these steps: ### Step 1: Analyze the Molecular Formula The molecular formula \( C_4H_8O \) indicates that the compound has 4 carbon atoms, 8 hydrogen atoms, and 1 oxygen atom. This suggests that the compound could be unsaturated (having double bonds) since the hydrogen count is lower than that of a saturated compound. **Hint:** Look for the degree of unsaturation using the formula \( \text{Degree of Unsaturation} = \frac{(2C + 2 - H)}{2} \). ### Step 2: Test for Unsaturation The compound is said to decolorize bromine water, which is a test for unsaturation. This indicates that X must contain at least one double bond between carbon atoms (C=C). **Hint:** Remember that alkenes and alkynes can decolorize bromine water due to their double or triple bonds. ### Step 3: Identify Possible Structures We will consider possible structures for \( C_4H_8O \) that can decolorize bromine water. The following structures could be considered: 1. Butene (C4H8) 2. 2-butanol (C4H10O) 3. 3-buten-2-ol (C4H8O) 4. 2-butanone (C4H8O) Among these, we need to check which of these compounds can decolorize bromine water. **Hint:** Focus on structures that contain C=C bonds. ### Step 4: React with Iodine and Sodium Hydroxide The question states that X reacts with iodine (I2) and sodium hydroxide (NaOH) to give a yellow precipitate. This reaction is characteristic of the iodoform test, which indicates the presence of a methyl ketone or a secondary alcohol with a methyl group adjacent to the hydroxyl group. **Hint:** Look for compounds that can produce a yellow precipitate when treated with iodine and NaOH. ### Step 5: Determine the Structure of X Among the identified structures, we need to check which one can give a yellow precipitate: - **2-butanol** (secondary alcohol with a methyl group adjacent) will give a yellow precipitate. - **2-butenone** (methyl ketone) will also give a yellow precipitate. However, since the compound must also decolorize bromine water, we can conclude that **2-butanol** is the correct structure because it is a secondary alcohol that meets both criteria. **Hint:** Verify the structure by checking if it meets both the unsaturation and iodoform test requirements. ### Conclusion Thus, the compound X is **2-butanol** (or 2-butanone, depending on the context, but primarily 2-butanol fits both tests). **Final Answer:** The compound X is **2-butanol**.

To identify the compound X with the molecular formula \( C_4H_8O \), we will follow these steps: ### Step 1: Analyze the Molecular Formula The molecular formula \( C_4H_8O \) indicates that the compound has 4 carbon atoms, 8 hydrogen atoms, and 1 oxygen atom. This suggests that the compound could be unsaturated (having double bonds) since the hydrogen count is lower than that of a saturated compound. **Hint:** Look for the degree of unsaturation using the formula \( \text{Degree of Unsaturation} = \frac{(2C + 2 - H)}{2} \). ### Step 2: Test for Unsaturation ...
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RESONANCE ENGLISH-STRUCTURAL IDENTIFICATION & PRACTICAL ORGANIC CHEMISTRY-Part-III
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  3. X' compound (C(4)H(8)O) decolorises bromine water react with I(2) & Na...

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  4. Compounds I and II can be distinguished by using reagent. {:("(I)",,...

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