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In a compound oxide ions are arranged in...

In a compound oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-sixth of the tetrahedral voids and cations B occupy one-third of the octahdral voids. The formual of the compound is `A_(x), B_(y), O_(z)` then find the value of `x + y + z`

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To solve the problem, we need to determine the values of x, y, and z in the formula \( A_x B_y O_z \) based on the arrangement of ions in the compound. ### Step-by-Step Solution: 1. **Identify the Arrangement of Oxide Ions**: - The oxide ions (O²⁻) are arranged in a cubic close packing (CCP) arrangement, which is equivalent to a face-centered cubic (FCC) structure. 2. **Calculate the Number of Oxide Ions**: - In a face-centered cubic (FCC) structure, the number of atoms (or ions) is given by: \[ \text{Number of atoms} = \frac{1}{8} \times 8 + \frac{1}{2} \times 6 = 1 + 3 = 4 \] - Therefore, there are 4 oxide ions (O²⁻) in the unit cell. 3. **Determine the Number of Tetrahedral and Octahedral Voids**: - In a FCC structure: - The number of tetrahedral voids = 8 - The number of octahedral voids = 4 4. **Calculate the Number of Cations A and B**: - Cation A occupies one-sixth of the tetrahedral voids: \[ \text{Cations A} = \frac{1}{6} \times 8 = \frac{8}{6} = \frac{4}{3} \] - Cation B occupies one-third of the octahedral voids: \[ \text{Cations B} = \frac{1}{3} \times 4 = \frac{4}{3} \] 5. **Write the Empirical Formula**: - From the calculations, we have: - \( A = \frac{4}{3} \) - \( B = \frac{4}{3} \) - \( O = 4 \) - Thus, the formula can be expressed as: \[ A_{\frac{4}{3}} B_{\frac{4}{3}} O_4 \] 6. **Normalize the Formula**: - To express the formula in whole numbers, we can multiply each coefficient by 3: \[ A_{4} B_{4} O_{12} \] - This simplifies to: \[ A_{1} B_{1} O_{3} \quad \text{(after dividing by 4)} \] 7. **Identify x, y, z**: - From the normalized formula \( A_1 B_1 O_3 \), we find: - \( x = 1 \) - \( y = 1 \) - \( z = 3 \) 8. **Calculate x + y + z**: - Finally, we calculate: \[ x + y + z = 1 + 1 + 3 = 5 \] ### Final Answer: The value of \( x + y + z \) is **5**.
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