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Formula of ferrocene is :...

Formula of ferrocene is :

A

`[Fe(CN)_(4)]^(4-)`

B

`[Fe(CN)_(6)]^(3+)`

C

`[Fe(CO)_(5)]`

D

`[Fe(C_(5)H_(5))_(2)]`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the formula of ferrocene, we can follow these steps: ### Step 1: Understand the Structure of Ferrocene Ferrocene is a type of coordination compound known as a "sandwich" compound. It consists of two cyclopentadienyl (C5H5) rings that are symmetrically arranged around a central iron (Fe) atom. **Hint:** Remember that "sandwich" compounds have a central metal atom surrounded by two ligands. ### Step 2: Identify the Ligands Each cyclopentadienyl ring (C5H5) acts as a ligand. Cyclopentadiene itself has a formula of C5H6, but when it acts as a ligand, it loses a hydrogen atom and carries a negative charge, becoming C5H5⁻. **Hint:** Ligands can change their formula when they coordinate with a metal, often losing a hydrogen atom. ### Step 3: Determine the Charge on the Iron Atom In ferrocene, there are two cyclopentadienyl ligands, each with a charge of -1. Therefore, the total negative charge from the two ligands is -2. To balance this, the iron atom must have a +2 charge (Fe²⁺). **Hint:** The overall charge of the complex must be neutral; balance the charges from the ligands with the charge on the metal. ### Step 4: Write the Formula Since there are two cyclopentadienyl ligands and one iron atom, we can write the formula for ferrocene as: \[ \text{Fe(C}_5\text{H}_5\text{)}_2 \] **Hint:** When writing the formula, remember to indicate the number of ligands by using subscripts. ### Final Answer The formula of ferrocene is: \[ \text{Fe(C}_5\text{H}_5\text{)}_2 \] ### Summary of Steps: 1. Understand the structure of ferrocene as a sandwich compound. 2. Identify the ligands (cyclopentadienyl rings). 3. Determine the charge on the iron atom. 4. Write the complete formula based on the number of ligands and the metal.
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Knowledge Check

  • The empirical formula of the compound is CH_(2)O , the possible molecular formula can be

    A
    `C_(3)H_(6)O_(3)`
    B
    `C_(2)H_(4)O`
    C
    `C_(4)H_(3)O_(2)`
    D
    `C_(4)H_(6)O_(2)`
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