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The correct statement on the isomerism a...

The correct statement on the isomerism associated with the following complex ions.
(a) `[ Ni(H_(2)O)_(5) NH_(3) ]^(2+)`
(b) `[Ni(H_(2)O) _(4) ( NH_(3))_(2) ]^(2+)` and
(c ) `[Ni(H_(2)O)_(3) ( NH_(3))_(3)]^(2+)` is `:`

A

(a) and (b) show only geometrical isomerism

B

(b) and ( c) show geometrical and optical isomerism

C

(b) and (c ) show only geomterical isomerism

D

(a) and (b) show geometrical and optical isomerism

Text Solution

Verified by Experts

The correct Answer is:
C
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The correct statement on the isomerism associated with the following complex ions. I [Ni(H_(2)O)_(5) NH_(3)]^(2+) II . [Ni (H_(2) O)_(4) (NH_(3))_(2)]^(2+) III. [Ni(H_(2)O)_(3)(NH_(3))_(3)]^(2+)

Amongs the following which will show geometrical isomerism. (a) [Ni(NH_(3))_(5)Cl]^+ (b) [Ni(NH_(3))_(4)ClBr] (c) [Ni(NH_(3))_(3)Cl]^+ (d) [Ni(NH_(3))_(2)(NO_(2)_(2)]

What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

Correct order of magnetic moment (spin only) for the following complexes (a) [Pd(PPh_(3))_(2)Cl_(2)] (b) [Ni(CO)_(4)] (c) [Ni(CN)_(4)]^(2-) (d) [Ni(H_(2)O)_(6)]^(2+)

Which of the following statement is not correct ? (a) [Ni(H_(2)O)_(6)]^(2+) and [Ni(NH_(3))_(6)]^(2+) have same value of CFSE ( b) [Ni(H_(2)O)_(6)]^(2+) and [Ni(NH_(3))_(6)]^(2+) have same value of magnetic moment

Among the following optical activity is possible in (a) [Co(H_(2)O)_(2)(NH_(3))_(3)CI]^(o+) (b) [Co(H_(2)O))_(4)CI_(2)]^(o+)] (c ) [Co(NH_(3))_(4)(NO_(2))CI]^(o+) (d) [Co(CN)_(5)NC]^(Θ) .

The correct decreasing order of basic strength of the following species is ….. H_(2)O, NH_(3), OH^(-),NH_(2)^(-)

NiCl_(2)+NH_(3)(excess)to [Ni(NH_(3))_(6)]^(2+)

NiCl_(2)+NH_(3)(excess)to [Ni(NH_(3))_(6)]^(2+)

Which of the following is true about the complex [PtCl_(2)(H_(2)O)(NH_(3))] ?

RESONANCE ENGLISH-COORDINATION COMPOUNDS-Exercise-3 Online Exam
  1. Which of the following formula representation is NOT correct?

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  2. Consider the coordination compound , [Co(NH(3))(6)]Cl(3). In the forma...

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  3. Among the following species the one which causes the highest CFSE, De...

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  4. Which of the following complex ions is expected to absorb visible ligh...

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  5. An octahedral complex with molecular composition M.5NH(3).Cl.SO(4) has...

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  6. Nickel (Z = 28) combines with a uninegative monodentate ligand to form...

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  7. The correct statement on the isomerism associated with the following c...

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  8. Which molecule/ion among the following cannot act as a ligand in compl...

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  9. Which of the following complex ions has electrons that are symmetrical...

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  10. Identify the correct trend given below: (Atomic No = Ti : 22 , Cr : ...

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  11. Which one of the following complexes will consume more equivalent of a...

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  12. Which of the following is an example of homoleptic complex ?

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  13. sp^(3)d^(2) hybridization is not displayed by :

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  14. [Co(2)(CO)(8)] displays :

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  15. The correct combination is :

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  16. The correct order of spin-only magnetic moments among the following is...

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  17. The total number of possible isomers of sqaure-planar [Pt(Cl)(NO(2))(N...

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  18. In a complexometric titration of metal ion with ligand M("Metal ion"...

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  19. In Wilkinson's catalyst, the hybrid state of central metal ion and shp...

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  20. Which of the following compound will show geometrical isomerism?

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