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Ph-NO(2) overset(Sn//HCl)rarr underset("...

`Ph-NO_(2) overset(Sn//HCl)rarr underset("HCl, " 0^(@)C-5^(@)C)overset(NaNO_(2))rarr underset(Ph-OH)overset("Basic medium")rarr "Product Y"`
Find the molecular weight of Y report your answer as `underset(2)overset("Molecular weight")rarr`

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The correct Answer is:
To solve the problem, we need to follow the sequence of reactions step by step and determine the final product (Y) and its molecular weight. ### Step 1: Identify the starting compound The starting compound is **Ph-NO₂** (Nitrobenzene). The molecular structure can be represented as: - **C₆H₅-NO₂** ### Step 2: First reaction with Sn and HCl The first reaction involves the reduction of nitrobenzene (Ph-NO₂) using tin (Sn) and hydrochloric acid (HCl). This reaction converts the nitro group (-NO₂) into an amino group (-NH₂), resulting in: - **Ph-NH₂** (Aniline) ### Step 3: Second reaction with NaNO₂ in HCl at low temperature The aniline (Ph-NH₂) then reacts with sodium nitrite (NaNO₂) in hydrochloric acid (HCl) at low temperatures. This reaction forms a diazonium salt: - **Ph-N₂⁺Cl⁻** (Benzene diazonium chloride) ### Step 4: Third reaction with phenol in basic medium Next, the diazonium salt reacts with phenol (C₆H₅-OH) in a basic medium. The -OH group of phenol replaces the diazonium group, leading to the formation of: - **Ph-O-N=N-Ph** (P-hydroxy azo benzene) ### Step 5: Determine the molecular formula of Product Y The molecular formula of P-hydroxy azo benzene can be derived as follows: - The structure consists of: - 12 Carbon (C) atoms - 10 Hydrogen (H) atoms - 2 Nitrogen (N) atoms - 1 Oxygen (O) atom Thus, the molecular formula is **C₁₂H₁₀N₂O**. ### Step 6: Calculate the molecular weight of Product Y Now we calculate the molecular weight using the atomic weights: - Carbon (C): 12 g/mol - Hydrogen (H): 1 g/mol - Nitrogen (N): 14 g/mol - Oxygen (O): 16 g/mol Now, we can calculate the total molecular weight: - Molecular weight = (Number of C × Atomic weight of C) + (Number of H × Atomic weight of H) + (Number of N × Atomic weight of N) + (Number of O × Atomic weight of O) Calculating: - C: 12 × 12 = 144 - H: 10 × 1 = 10 - N: 2 × 14 = 28 - O: 1 × 16 = 16 Total molecular weight = 144 + 10 + 28 + 16 = **198 g/mol** ### Final Answer Thus, the molecular weight of Product Y is: \[ \underset{2}{\overset{\text{Molecular weight}}{\rightarrow}} 198 \]
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