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major product of the following reaction ...

major product of the following reaction is : `CH_(3)CH=CHCO_(2)CH_(3) overset("LiAIH"_(4))rarr`

A

`CH_(3)CH_(2)CH_(2)CHO`

B

`CH_(3)CH_(2)CH_(2)CO_(2)CH_(3)`

C

`CH_(3)CH_(2)CH_(2)OH`

D

`CH_(3)CH=CHCH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the reaction between `CH₃CH=CHCO₂CH₃` (an ester) and lithium aluminium hydride (LiAlH₄), we can follow these steps: ### Step 1: Identify the Functional Groups The compound `CH₃CH=CHCO₂CH₃` contains an alkene (the `CH=CH` part) and an ester functional group (`CO₂CH₃`). ### Step 2: Understand the Reactivity of LiAlH₄ Lithium aluminium hydride is a strong reducing agent that can reduce esters to primary alcohols. In this case, the ester will be reduced. ### Step 3: Mechanism of Reduction 1. The hydride ion (H⁻) from LiAlH₄ attacks the carbonyl carbon of the ester. 2. This forms a tetrahedral intermediate. 3. The alkoxy group (the `OCH₃` part) leaves, resulting in the formation of an aldehyde. 4. The aldehyde is then further reduced by another hydride from LiAlH₄ to form a primary alcohol. ### Step 4: Determine the Structure of the Product After the reduction: - The initial ester `CH₃CH=CHCO₂CH₃` will first be converted to an aldehyde. - The aldehyde will then be reduced to a primary alcohol. The final product will be `CH₃CH=CHCH₂OH`, which is a primary alcohol. ### Step 5: Conclusion The major product of the reaction between `CH₃CH=CHCO₂CH₃` and LiAlH₄ is `CH₃CH=CHCH₂OH`. ### Final Answer The major product is `CH₃CH=CHCH₂OH`. ---

To determine the major product of the reaction between `CH₃CH=CHCO₂CH₃` (an ester) and lithium aluminium hydride (LiAlH₄), we can follow these steps: ### Step 1: Identify the Functional Groups The compound `CH₃CH=CHCO₂CH₃` contains an alkene (the `CH=CH` part) and an ester functional group (`CO₂CH₃`). ### Step 2: Understand the Reactivity of LiAlH₄ Lithium aluminium hydride is a strong reducing agent that can reduce esters to primary alcohols. In this case, the ester will be reduced. ...
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