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Among the following, the molecule expect...

Among the following, the molecule expected to be stabilized by anion formation is : `C_(2), O_(2), NO, F_(2)`

A

`C_(2)`

B

NO

C

`O_(2)`

D

`F_(2)`

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The correct Answer is:
To determine which molecule is expected to be stabilized by anion formation among C2, O2, NO, and F2, we need to analyze the bond order of their respective anions. Here’s a step-by-step solution: ### Step 1: Understand the concept of anions An anion is a negatively charged ion that has gained one or more electrons. For each molecule, we will consider its anion and the total number of electrons it contains. ### Step 2: Count the total number of electrons for each molecule - **C2**: Each carbon atom contributes 4 valence electrons, so C2 has a total of 8 electrons. The anion C2^- will have 9 electrons. - **O2**: Each oxygen atom contributes 6 valence electrons, so O2 has a total of 12 electrons. The anion O2^- will have 13 electrons. - **NO**: Nitrogen contributes 5 electrons and oxygen contributes 6 electrons, so NO has a total of 11 electrons. The anion NO^- will have 12 electrons. - **F2**: Each fluorine atom contributes 7 valence electrons, so F2 has a total of 14 electrons. The anion F2^- will have 15 electrons. ### Step 3: Write the molecular orbital configuration We will use the general molecular orbital configuration for diatomic molecules to determine the bond order. 1. **C2^- (9 electrons)**: - Configuration: σ1s² σ*1s² σ2s² σ*2s² σ2p_z² π2p_x² π2p_y¹ - Bonding electrons = 9, Antibonding electrons = 4 - Bond order = (Bonding - Antibonding) / 2 = (9 - 4) / 2 = 2.5 2. **O2^- (13 electrons)**: - Configuration: σ1s² σ*1s² σ2s² σ*2s² σ2p_z² π2p_x² π2p_y² - Bonding electrons = 10, Antibonding electrons = 3 - Bond order = (10 - 3) / 2 = 3.5 3. **NO^- (12 electrons)**: - Configuration: σ1s² σ*1s² σ2s² σ*2s² σ2p_z² π2p_x² - Bonding electrons = 8, Antibonding electrons = 4 - Bond order = (8 - 4) / 2 = 2.0 4. **F2^- (15 electrons)**: - Configuration: σ1s² σ*1s² σ2s² σ*2s² σ2p_z² π2p_x² π2p_y² - Bonding electrons = 12, Antibonding electrons = 3 - Bond order = (12 - 3) / 2 = 4.5 ### Step 4: Compare bond orders From the calculations: - C2^- has a bond order of 2.5 - O2^- has a bond order of 3.5 - NO^- has a bond order of 2.0 - F2^- has a bond order of 4.5 ### Step 5: Conclusion The anion with the highest bond order is **F2^-** with a bond order of 4.5, indicating that it is the most stable anion among the given options. ### Final Answer The molecule expected to be stabilized by anion formation is **F2**.

To determine which molecule is expected to be stabilized by anion formation among C2, O2, NO, and F2, we need to analyze the bond order of their respective anions. Here’s a step-by-step solution: ### Step 1: Understand the concept of anions An anion is a negatively charged ion that has gained one or more electrons. For each molecule, we will consider its anion and the total number of electrons it contains. ### Step 2: Count the total number of electrons for each molecule - **C2**: Each carbon atom contributes 4 valence electrons, so C2 has a total of 8 electrons. The anion C2^- will have 9 electrons. - **O2**: Each oxygen atom contributes 6 valence electrons, so O2 has a total of 12 electrons. The anion O2^- will have 13 electrons. ...
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