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The species that can have a trans-isomer...

The species that can have a trans-isomer is: (en = ethane -1,2-diamine, ox = oxalate)

A

`[Pt(en)Cl_(2)]`

B

`[Pt(en)_(2)Cl_(2)]^(2+)`

C

`[Zn(en)Cl_(2)]`

D

`[Cr(en)_(2)("ox")]^(+)`

Text Solution

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The correct Answer is:
To determine which species can have a trans-isomer, we need to analyze the coordination complexes formed by the given ligands (ethane-1,2-diamine (en) and oxalate (ox)) with different metal ions. ### Step-by-Step Solution: 1. **Identify the Ligands and Their Properties:** - Ethane-1,2-diamine (en) is a bidentate ligand, meaning it can form two bonds with a metal center. - Oxalate (ox) is also a bidentate ligand. 2. **Analyze Each Option:** - **Option 1: [Pt(en)Cl2]** - Platinum (Pt) can have a coordination number of 4, leading to square planar geometry. - In a square planar arrangement, the two en ligands will occupy adjacent positions, and the two Cl ligands will also occupy adjacent positions. This arrangement does not allow for trans isomerism. - **Option 2: [Pt(en)2Cl2]** - Here, platinum has a coordination number of 6, leading to an octahedral geometry. - The two en ligands can be placed opposite each other, allowing the two Cl ligands to also be opposite each other. This arrangement permits the formation of a trans isomer. - **Option 3: [Zn(en)Cl2]** - Zinc typically has a coordination number of 4, leading to tetrahedral geometry. - In a tetrahedral arrangement, all ligands are equivalent and cannot exhibit trans isomerism. - **Option 4: [Cr(en)2(ox)]** - Chromium in this case has a coordination number of 6, leading to an octahedral geometry. - The two en ligands can be placed adjacent to each other, and the oxalate can occupy the remaining positions. This arrangement does not allow for trans isomerism. 3. **Conclusion:** - The only complex that can exhibit trans isomerism is **Option 2: [Pt(en)2Cl2]**. ### Final Answer: The species that can have a trans-isomer is **Option 2: [Pt(en)2Cl2]**.

To determine which species can have a trans-isomer, we need to analyze the coordination complexes formed by the given ligands (ethane-1,2-diamine (en) and oxalate (ox)) with different metal ions. ### Step-by-Step Solution: 1. **Identify the Ligands and Their Properties:** - Ethane-1,2-diamine (en) is a bidentate ligand, meaning it can form two bonds with a metal center. - Oxalate (ox) is also a bidentate ligand. ...
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