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In Sc^(3+),Ti^(2+),Ti^(3+),V^(2+) increa...

In `Sc^(3+),Ti^(2+),Ti^(3+),V^(2+)` increasing order of spin only magnetic moment is:

A

1. `V^(+) lt Ti^(2+) lt Ti^(3+) lt Sc^(3+)`

B

2. `Sc^(3+) lt Ti^(3+) lt V^(2+) lt Ti^(2+)`

C

3. `Sc^(3+) lt Ti^(3+) lt Ti^(2+) lt V^(2+)`

D

4. `Ti^(3+) lt Ti^(2+) lt Sc^(3+) lt V^(2+)`

Text Solution

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The correct Answer is:
To determine the increasing order of spin-only magnetic moments for the ions Sc^(3+), Ti^(2+), Ti^(3+), and V^(2+), we will follow these steps: ### Step 1: Identify the number of electrons in each ion - **Sc^(3+)**: Scandium has an atomic number of 21. Therefore, Sc^(3+) has 21 - 3 = 18 electrons. - **Ti^(2+)**: Titanium has an atomic number of 22. Therefore, Ti^(2+) has 22 - 2 = 20 electrons. - **Ti^(3+)**: Ti^(3+) has 22 - 3 = 19 electrons. - **V^(2+)**: Vanadium has an atomic number of 23. Therefore, V^(2+) has 23 - 2 = 21 electrons. ### Step 2: Determine the electron configuration for each ion - **Sc^(3+)**: The electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ (completely filled) → 0 unpaired electrons. - **Ti^(2+)**: The electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d² → 2 unpaired electrons. - **Ti^(3+)**: The electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹ → 1 unpaired electron. - **V^(2+)**: The electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d³ → 3 unpaired electrons. ### Step 3: Calculate the spin-only magnetic moment using the formula The formula for the spin-only magnetic moment (μ) is: \[ \mu = \sqrt{n(n + 2)} \] where n is the number of unpaired electrons. - **Sc^(3+)**: n = 0 \[ \mu = \sqrt{0(0 + 2)} = 0 \, \text{Bohr magneton} \] - **Ti^(2+)**: n = 2 \[ \mu = \sqrt{2(2 + 2)} = \sqrt{8} = 2\sqrt{2} \, \text{Bohr magneton} \] - **Ti^(3+)**: n = 1 \[ \mu = \sqrt{1(1 + 2)} = \sqrt{3} \, \text{Bohr magneton} \] - **V^(2+)**: n = 3 \[ \mu = \sqrt{3(3 + 2)} = \sqrt{15} \, \text{Bohr magneton} \] ### Step 4: Arrange the magnetic moments in increasing order Now we can summarize the magnetic moments: - Sc^(3+): 0 Bohr magneton - Ti^(3+): √3 Bohr magneton - Ti^(2+): 2√2 Bohr magneton - V^(2+): √15 Bohr magneton To compare: - 0 < √3 < 2√2 < √15 ### Final Answer The increasing order of spin-only magnetic moment is: \[ \text{Sc}^{3+} < \text{Ti}^{3+} < \text{Ti}^{2+} < \text{V}^{2+} \]

To determine the increasing order of spin-only magnetic moments for the ions Sc^(3+), Ti^(2+), Ti^(3+), and V^(2+), we will follow these steps: ### Step 1: Identify the number of electrons in each ion - **Sc^(3+)**: Scandium has an atomic number of 21. Therefore, Sc^(3+) has 21 - 3 = 18 electrons. - **Ti^(2+)**: Titanium has an atomic number of 22. Therefore, Ti^(2+) has 22 - 2 = 20 electrons. - **Ti^(3+)**: Ti^(3+) has 22 - 3 = 19 electrons. - **V^(2+)**: Vanadium has an atomic number of 23. Therefore, V^(2+) has 23 - 2 = 21 electrons. ...
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