Home
Class 12
CHEMISTRY
The number of bonds between carbon and o...

The number of bonds between carbon and oxygen atoms in major product of the following reaction is________.
`CH_(3)overset(OH)overset(|)(CHCH_(2)CH_(2)NH_(2)) overset("ethyl formate (1 equiv)")underset("triethylam in e")to`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the number of bonds between carbon and oxygen atoms in the major product of the given reaction, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are 3-aminobutane (CH₃CH(CH₂)CH₂NH₂) and ethyl formate (HCOOC₂H₅). 2. **Determine the Reaction Mechanism**: In this reaction, the carbonyl carbon of ethyl formate will be attacked by the nitrogen atom of the amine (3-aminobutane) because nitrogen is less electronegative than oxygen and has a lone pair available for donation. 3. **Formation of the Intermediate**: When nitrogen attacks the carbonyl carbon, the carbonyl double bond (C=O) breaks. This results in the formation of a tetrahedral intermediate where the nitrogen is bonded to the carbon, and the oxygen carries a negative charge (O⁻). 4. **Rearrangement and Elimination**: The tetrahedral intermediate will rearrange, and the negatively charged oxygen will facilitate the departure of the ethyl group (C₂H₅O⁻), resulting in the formation of a new carbon-nitrogen bond. 5. **Final Product Structure**: After the rearrangement, the major product is a compound where the nitrogen is bonded to the carbon chain, and the carbonyl carbon is now bonded to a hydroxyl group (OH) and a carbonyl oxygen (C=O). 6. **Count the Bonds**: In the final product, we have: - One carbon-oxygen double bond (C=O) which is a pi bond. - One carbon-oxygen single bond (C-O) which is a sigma bond. - Another carbon-oxygen single bond (C-O) from the hydroxyl group (OH). Therefore, the total number of bonds between carbon and oxygen in the product is: - 1 sigma bond (from C-O in OH) - 1 sigma bond (from C-O in C=O) - 1 pi bond (from C=O) This gives us a total of **3 bonds** (2 sigma bonds and 1 pi bond) between carbon and oxygen. ### Final Answer: The number of bonds between carbon and oxygen atoms in the major product of the reaction is **3**.

To solve the question regarding the number of bonds between carbon and oxygen atoms in the major product of the given reaction, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are 3-aminobutane (CH₃CH(CH₂)CH₂NH₂) and ethyl formate (HCOOC₂H₅). 2. **Determine the Reaction Mechanism**: In this reaction, the carbonyl carbon of ethyl formate will be attacked by the nitrogen atom of the amine (3-aminobutane) because nitrogen is less electronegative than oxygen and has a lone pair available for donation. ...
Promotional Banner

Topper's Solved these Questions

  • JEE MAIN REVISION TEST -14

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTON 2)|5 Videos
  • JEE MAIN REVISION TEST - 7|JEE - 2020

    VMC MODULES ENGLISH|Exercise Chemistry (Section - 2) Numercial Value type|5 Videos
  • JEE MAIN REVISION TEST -17 (2020)

    VMC MODULES ENGLISH|Exercise CHEMISTRY|25 Videos

Similar Questions

Explore conceptually related problems

The major product of the following reaction is : CH_(3)overset(OH)overset(|)(C)HCH_(2)CH_(2)NH_(2)overset("ethyl formate(1 equiv.)")underset("triethylamine")rarr

The major product of the following reaction is CH_(3)C-=CH underset((ii) DI)overset((i) DCl(1 "equiv")) to

The major product formed in the following reaction is : CH_3CH = CHCH(CH_3)_2 overset(HBr)(to)

What is the major product obtained from the following reactions ? HOCH_(2)overset(O)overset(||)(C)OH overset(SOCl_(2))to overset(CH_(3)OH)to

The major product of the following reaction is : CH_(3)C-=CH overset((i)DCl(1 "equiv".))underset((ii)DI)rarr

The major product of the following reaction is : CH_(3)underset(overset(|)(Br))(C)HCH_(2)underset(overset(|)(Br))(C)HCH_(2)CH_(3) underset("heat")overset(KOH, CH_(3)OH)(to)

The major product [B] in the following reaction is : CH_(3)-CH_(3)-overset(CH)overset("| ")"CH"-CH_(2)-OCH_(2)-CH_(3)overset(HI)underset("Heat")rarr [A]" alcohol"overset(H_(2)SO_(4))underset(Delta)rarr [B]

What is the major product formed in the following reaction CH_(3)O -overset(OH)overset(|)(CH) -underset(CH_(3))underset(|)(CH)-CH_(3) + HBr to

The major product of the following reaction is: CH_(3)-underset(H)underset(|)overset(CH_(3))overset(|)C-underset(Br)underset(|)(CHCH_(3)) overset(CH_(3)OH) to