Home
Class 12
CHEMISTRY
For a reaction having rate constant k at...

For a reaction having rate constant k at a temperature T, when a graph between ln k and 1/T is drawn a straight line is obtained. The point at which line cuts y -axis and x -axis respectively correspond to the temperature:

A

`0, (Ea)/(2.303R)log A`

B

`oo , (E_(a))/("R ln A")`

C

`0, log A`

D

None of these.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will use the Arrhenius equation and analyze the graph of ln k versus 1/T. ### Step-by-Step Solution: 1. **Understand the Arrhenius Equation**: The Arrhenius equation is given by: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) = rate constant - \( A \) = Arrhenius constant (pre-exponential factor) - \( E_a \) = activation energy - \( R \) = universal gas constant - \( T \) = temperature in Kelvin 2. **Take the Natural Logarithm**: Taking the natural logarithm of both sides gives: \[ \ln k = \ln A - \frac{E_a}{RT} \] This can be rearranged to: \[ \ln k = \ln A - \frac{E_a}{R} \cdot \frac{1}{T} \] 3. **Identify the Linear Form**: The equation can be compared to the linear form \( y = mx + c \): - Let \( y = \ln k \) - Let \( x = \frac{1}{T} \) - The slope \( m = -\frac{E_a}{R} \) - The y-intercept \( c = \ln A \) 4. **Determine the Intercepts**: - **Y-Intercept**: When \( \frac{1}{T} = 0 \) (i.e., \( T \to \infty \)), the value of \( \ln k \) at this point is \( \ln A \). Thus, the y-intercept corresponds to \( T = \infty \). - **X-Intercept**: When \( \ln k = 0 \), we can set the equation to zero: \[ 0 = \ln A - \frac{E_a}{R} \cdot \frac{1}{T} \] Rearranging gives: \[ \frac{E_a}{R} \cdot \frac{1}{T} = \ln A \] Therefore, solving for \( T \): \[ T = \frac{E_a}{R \ln A} \] 5. **Final Results**: - The y-intercept corresponds to \( T \to \infty \). - The x-intercept corresponds to \( T = \frac{E_a}{R \ln A} \). ### Summary: - The point where the line cuts the y-axis corresponds to \( T = \infty \). - The point where the line cuts the x-axis corresponds to \( T = \frac{E_a}{R \ln A} \).

To solve the problem, we will use the Arrhenius equation and analyze the graph of ln k versus 1/T. ### Step-by-Step Solution: 1. **Understand the Arrhenius Equation**: The Arrhenius equation is given by: \[ k = A e^{-\frac{E_a}{RT}} ...
Promotional Banner

Topper's Solved these Questions

  • JEE MAIN REVISION TEST - 26 (2020)

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION 2)|5 Videos
  • JEE MAIN REVISION TEST - 25 | JEE - 2020

    VMC MODULES ENGLISH|Exercise CHEMISTRY|25 Videos
  • JEE MAIN REVISION TEST - 27 - JEE -2020

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION 2)|5 Videos

Similar Questions

Explore conceptually related problems

The graph between log k versus 1//T is a straight line.

Find the equation of a line which cuts an intercept of 3 and -4 units from X -axis and Y -axis respectively.

Find the equation of the straight line whose intercepts on X-axis and Y-axis are respectively twice and thrice of those by the line 3x+4y=12.

At constant temperature if a graph plotted between logP and log((1)/(V)) has an intercept of unity then what will be the value of constant (k)

A straight line through the point (1,1) meets the X-axis at A and Y-axis at B. The locus of the mid-point of AB is

The x-t graph of an object is a straight line inclined to time-axis. What does this statement indicate ?

The graph pressure versus temperature (T) at constant volume is a straight line.(T/F)

Find the equation of the line perpendicular to the line x/a-y/b=1 and passing through a point at which it cuts the x-axis.

Find the equation of the line perpendicular to the line x/a-y/b=1 and passing through a point at which it cuts the x-axis.

If a graph is plotted between log (a-x) and t , the slope of the straight line is equal to -0.03 . The specific reaction rate will be