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The compound that does not give a blue c...

The compound that does not give a blue color in Lassaigne's test is

A

`C_(6)H_(5) - NH_(2)`

B

`CH_(3)CONH_(2)`

C

`NH_(2) - NH_(2)`

D

`C_(6)H_(5) - NO_(2)`

Text Solution

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The correct Answer is:
To solve the question regarding which compound does not give a blue color in Lassaigne's test, we can follow these steps: ### Step 1: Understand Lassaigne's Test Lassaigne's test is a qualitative analysis technique used to detect the presence of nitrogen in organic compounds. When a compound containing nitrogen is heated with sodium metal, it forms sodium cyanide, which can then react with copper(II) sulfate to produce a blue color, indicating the presence of nitrogen. ### Step 2: Identify the Compounds The compounds given in the question are: 1. C6H5NH2 (Aniline) 2. CH3CONH2 (Acetamide) 3. NH2C6H5 (Phenylamine) 4. C6H5NO2 (Nitrobenzene) ### Step 3: Analyze Each Compound - **C6H5NH2 (Aniline)**: Contains carbon and nitrogen. It will give a blue color in Lassaigne's test. - **CH3CONH2 (Acetamide)**: Contains carbon and nitrogen. It will also give a blue color in Lassaigne's test. - **NH2C6H5 (Phenylamine)**: Contains carbon and nitrogen. It will give a blue color in Lassaigne's test. - **C6H5NO2 (Nitrobenzene)**: Contains carbon and nitrogen. It will give a blue color in Lassaigne's test. ### Step 4: Identify the Compound Without Carbon From the analysis, we see that all the compounds listed contain carbon. However, if the question had included a compound that does not contain carbon (like a simple amine such as NH3), that would not give a blue color in Lassaigne's test. ### Conclusion Since all the given options contain carbon and nitrogen, we can conclude that none of the provided options fit the criteria of not giving a blue color in Lassaigne's test. However, if we were to consider a hypothetical compound without carbon, it would not yield a blue color. ### Final Answer The compound that does not give a blue color in Lassaigne's test is not present among the options provided. However, if we consider a compound without carbon, such as NH3, it would not give a blue color.

To solve the question regarding which compound does not give a blue color in Lassaigne's test, we can follow these steps: ### Step 1: Understand Lassaigne's Test Lassaigne's test is a qualitative analysis technique used to detect the presence of nitrogen in organic compounds. When a compound containing nitrogen is heated with sodium metal, it forms sodium cyanide, which can then react with copper(II) sulfate to produce a blue color, indicating the presence of nitrogen. ### Step 2: Identify the Compounds The compounds given in the question are: 1. C6H5NH2 (Aniline) ...
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Which compound does not give positive test in Lassaigne's test for nitrogen ?

Qualitative analysis of organic compounds is performed by Lassaigne's test by fusion with metallic sodium, by which the covalent compounds are converted into ionic compounds. Extra elementsline N,S,P andhalogensaredetected by their usual tests. Q. Which of the following will give blood-red colour in lassaigne's test for nitrogen

Knowledge Check

  • A compound which does not give a positive tests in lassaigne's test for nitrogen is

    A
    urea
    B
    hydrazine
    C
    azobenzene
    D
    phenyl hydrazine
  • The compound which does not give iodoform test is

    A
    Acetophenone
    B
    Benzophenone
    C
    `CH_(3)underset(CH_(3))underset(|)CHOH`
    D
    `CH_(3)-underset(OH)underset(|)CH-CH_(2)CH_(2)CH_(3)`
  • The compound which does not give iodoform test is

    A
    Acetophenone
    B
    Benzophenone
    C
    `CH_(3)underset(CH_(3))underset(|)CHOH`
    D
    `CH_(3)-underset(OH)underset(|)CH-CH_(2)CH_(2)CH_(3)`
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