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PCl(5)+H(2)Oto B+HCI B+H(2)O to C+HCI ...

`PCl_(5)+H_(2)Oto B+HCI`
`B+H_(2)O to C+HCI`
The basicity of compound C will be:

A

1

B

3

C

2

D

none of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reactions step by step and determine the basicity of compound C. ### Step 1: Identify the first reaction The first reaction is: \[ \text{PCl}_5 + \text{H}_2\text{O} \rightarrow B + \text{HCl} \] In this reaction, phosphorus pentachloride (PCl5) reacts with water (H2O) to produce a compound B and hydrochloric acid (HCl). ### Step 2: Determine the product B From the hydrolysis of PCl5, we know that: \[ \text{PCl}_5 + \text{H}_2\text{O} \rightarrow \text{POCl}_3 + 2 \text{HCl} \] Thus, compound B is: \[ B = \text{POCl}_3 \] (phosphoryl chloride) ### Step 3: Identify the second reaction The second reaction is: \[ B + \text{H}_2\text{O} \rightarrow C + \text{HCl} \] Now, we will substitute B into this reaction: \[ \text{POCl}_3 + \text{H}_2\text{O} \rightarrow C + \text{HCl} \] ### Step 4: Determine the product C When POCl3 reacts with water, it undergoes hydrolysis to form: \[ \text{POCl}_3 + 3 \text{H}_2\text{O} \rightarrow \text{H}_3\text{PO}_4 + 3 \text{HCl} \] Thus, compound C is: \[ C = \text{H}_3\text{PO}_4 \] (orthophosphoric acid) ### Step 5: Determine the basicity of compound C The basicity of a compound refers to the number of hydrogen ions (H+) that can be donated by the compound. In the case of H3PO4, we can analyze its structure: - H3PO4 has three hydroxyl (OH) groups, each of which can donate one H+ ion. Therefore, the basicity of compound C (H3PO4) is 3. ### Final Answer The basicity of compound C (H3PO4) is **3**. ---

To solve the problem, we need to analyze the given reactions step by step and determine the basicity of compound C. ### Step 1: Identify the first reaction The first reaction is: \[ \text{PCl}_5 + \text{H}_2\text{O} \rightarrow B + \text{HCl} \] In this reaction, phosphorus pentachloride (PCl5) reacts with water (H2O) to produce a compound B and hydrochloric acid (HCl). ...
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