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The complex that can show optical isomer...

The complex that can show optical isomerism is:

A

`cis-[CrCl_(2)(o x)_(2)]^(-3)`

B

`trans -[CrCl_(2)(o x)_(2)]^(-3)`

C

Both (A) & (B)

D

Neither (A) and (B)

Text Solution

AI Generated Solution

The correct Answer is:
To determine which complex can show optical isomerism, we need to understand the concept of optical isomerism and the types of complexes that can exhibit this property. ### Step-by-Step Solution: 1. **Understanding Optical Isomerism**: - Optical isomerism occurs when two compounds have the same molecular formula and connectivity but differ in their spatial arrangement, making them non-superimposable mirror images (enantiomers). - These isomers will rotate plane-polarized light in different directions. 2. **Identifying the Complexes**: - The question mentions a specific complex: CrCl2OX^2-. - Here, Cr is the central metal ion (Chromium), Cl are monodentate ligands, and OX is a bidentate ligand. 3. **Analyzing the Structure**: - For the complex CrCl2OX^2-, we can visualize its cis and trans forms. - The **cis form** has the bidentate ligand OX adjacent to each other, while the **trans form** has them opposite each other. 4. **Cis Form Analysis**: - In the cis form, the arrangement of ligands creates a scenario where the complex can have non-superimposable mirror images. - This non-superimposability indicates that the cis form can exhibit optical isomerism. 5. **Trans Form Analysis**: - In the trans form, the arrangement of ligands allows for superimposable mirror images, meaning it does not exhibit optical isomerism. 6. **Conclusion**: - Therefore, the complex CrCl2OX^2- in its cis form can show optical isomerism, while the trans form cannot. ### Final Answer: The complex that can show optical isomerism is **CrCl2OX^2- (cis form)**.

To determine which complex can show optical isomerism, we need to understand the concept of optical isomerism and the types of complexes that can exhibit this property. ### Step-by-Step Solution: 1. **Understanding Optical Isomerism**: - Optical isomerism occurs when two compounds have the same molecular formula and connectivity but differ in their spatial arrangement, making them non-superimposable mirror images (enantiomers). - These isomers will rotate plane-polarized light in different directions. ...
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