Home
Class 12
CHEMISTRY
Each rubidium halide crystallising in th...

Each rubidium halide crystallising in the NaCl-type lattice has a unit cell length `0.30 Å` greater than that for corresponding potassium salt `(r_(k+)=1.33 Å`) of the same halogen. Hence, ionic radius of `Rb^(+)` is

A

`1.18 Å`

B

`1.43 Å`

C

`1.63 Å`

D

`1.03 Å`

Text Solution

AI Generated Solution

To find the ionic radius of \( Rb^+ \), we can follow these steps: ### Step 1: Understand the relationship between edge length and ionic radius in the NaCl-type lattice In a NaCl-type lattice, the relationship between the edge length \( a \) of the unit cell and the ionic radius \( r \) is given by the formula: \[ a = 2\sqrt{2}r \] ...
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise LEVEL-2|50 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise LEVEL-2 (Numerical Value Type for JEE Main )|15 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise LEVEL-0 ( Long Answer Type)|6 Videos
  • SURFACE CHEMISTRY

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|9 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos

Similar Questions

Explore conceptually related problems

Potassium crystallizes in body centered cubic lattice with a unit cell length a = 5.2 Å (A) what is the distance betweenn nearest neighbourss? (B) What is the distance between next nearest neighbour ? (C) How many nearest neighbours does each K atom have ? (D) How many next nearest neighbours does each K has ? (E) What is calculated density of crystalline K

The radius of chromium atom is 1.25Å . If it crystallises in body centred cubic lattice, calculate the length of the edge of the unit cell.

KCl crystallises in the same type of lattice as does NaCl Given that r_(Na^(+))//r_(Cl^(-))=0.55 and r_(K^(+))//r_(Cl^(-))=0.74 , the ratio of the side of unit cell for KCl to that of NaCl is

KCl crystallises in the same type of lattice as does NaCl Given that r_(Na^(+))//r_(Cl^(-))=0.55 and r_(K^(+))//r_(Cl^(-))=0.74 , the ratio of the side of unit cell for KCl to that of NaCl is

Aluminium metal (atomic weight = 27 g) crystallises in the cubic system with edge length 4.0 Å . The density of metal is 27.16 amu/ Å^(3) . Determine the unit cell type and calculate the radius of the Aluminium metal.

KCl crystallizes int the same type of lattic as done NaCl . Given that r_(Na^(+))//r_(Cl^(-)) = 0.50 and r_(Na^(+))//r_(K^(+)) = 0.70 , Calcualte the ratio of the side of the unit cell for KCl to that for NaCl:

KCl crystallizes int the same type of lattic as done NaCl . Given that r_(Na^(+))//r_(Cl^(-)) = 0.50 and r_(Na^(+))//r_(K^(+)) = 0.70 , Calcualte the ratio of the side of the unit cell for KCl to that for NaCl:

A solid cube of edge length =25.32 mm of an ionic compound which has NaCl type lattice is added to 1kg of water.The boiling point of this solution is found to be 100.52^@C (assume 100% ionisation of ionic compound).If radius of anion of ionic solid is 200 pm then calculate radius of cation of solid in pm (picometer). ( K_b of water =0.52 K kg "mole"^(-1) ,Avogadro's number, N_A=6xx10^(23),(root3(75))=4.22 )

A point source is emitting 0.2 W of ultravio- let radiation at a wavelength of lambda = 2537 Å . This source is placed at a distance of 1.0 m from the cathode of a photoelectric cell. The cathode is made of potassium (Work function = 2.22 eV ) and has a surface area of 4 cm^(2) . (a) According to classical theory, what time of exposure to the radiation shall be required for a potassium atom to accumulate sufficient energy to eject a photoelectron. Assume that radius of each potassium atom is 2 Å and it absorbs all energy incident on it. (b) Photon flux is defined as number of light photons reaching the cathode in unit time. Calculate the photon flux. (c) Photo efficiency is defined as probability of a photon being successful in knocking out an electron from the metal surface. Calculate the saturation photocurrent in the cell assuming a photo efficiency of 0.1. (d) Find the cut – off potential difference for the cell.

NaCl is a AB type of solid . Its crystalline structure is known as rock salt structure in which r_"Na"^+ and r_"Cl"^- are 95 and 181 pm respectively , where Cl^- is present at the lattice point of face centered cubic unit cell Na^+ ions are located in void and those compounds which have same crystalline structure also have same coordination system in which Na^+ and Cl^- ions are surrounded by certain number of opposite ions respectively. Under high pressure coordination number changes to 8 :8 type from 6 :6 type. LiCl adopts rock salt crystalline structure in which edge length is 5.40 Å. What would be the radii of Li^+ ?

VMC MODULES ENGLISH-THE SOLID STATE-LEVEL-1
  1. A compound of A and B crystallizes in a cubic lattice in which A atoms...

    Text Solution

    |

  2. Arrangement of sulphide ions in zinc blende is :

    Text Solution

    |

  3. Each rubidium halide crystallising in the NaCl-type lattice has a unit...

    Text Solution

    |

  4. A compound is formed by elements A and B. This crystallises in the cub...

    Text Solution

    |

  5. A solid compound is formed containing x , y and z atoms in a cubic lat...

    Text Solution

    |

  6. Sodium metal crystallizes in a body centred cubic lattice with a unit ...

    Text Solution

    |

  7. Number of unit cells in 4g of X(atomic mass=40). Which crystallises in...

    Text Solution

    |

  8. The 8 : 8 type of packing is present in :

    Text Solution

    |

  9. Crystal structure of NaCl is

    Text Solution

    |

  10. The coordination number of each atom in body centered cubic unit cell...

    Text Solution

    |

  11. Coordinating number of Na^(+) in NaCl is

    Text Solution

    |

  12. Which of the following statement is not correct?

    Text Solution

    |

  13. Which of the following statements is not about the voids ?

    Text Solution

    |

  14. In an antiflourite structure, cations occupy

    Text Solution

    |

  15. Number of tetrahedral void(s) per atom present in cubic closed pacled ...

    Text Solution

    |

  16. A compund is made of two elements P and Q are in ccp arrangement while...

    Text Solution

    |

  17. The fraction of total volume occupied by atoms in a simple cube is

    Text Solution

    |

  18. An alloy of copper, silver and gold is found to have copper constituti...

    Text Solution

    |

  19. Copper crystallises in fcc with a unit cell length of 361 pm. What is ...

    Text Solution

    |

  20. Which of the following does not exist ?

    Text Solution

    |