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Which of the following defects, if prese...

Which of the following defects, if present, lowers the density of the crystal ?

A

Frenkel defect

B

Schottky defect

C

F-centres

D

Interstitial defect

Text Solution

AI Generated Solution

To determine which defect lowers the density of a crystal, we need to analyze the types of defects present in crystalline solids. The two main types of defects we will consider are Frenkel defect and Schottky defect. ### Step-by-Step Solution: 1. **Understanding Frenkel Defect**: - In a Frenkel defect, a cation is displaced from its lattice site and occupies an interstitial site within the crystal. - This means that while one cation is missing from its original position, it is still present in the crystal structure, just in a different location (interstitial site). - Since the total number of ions remains the same, the overall mass of the crystal does not change. ...
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Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions. Which of the following defect, if present, lowers the density of the crystal ?

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VMC MODULES ENGLISH-THE SOLID STATE-LEVEL-1
  1. If a cation leaves a site in solid lattice, and is located at an inter...

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  2. Schottky defect occurs mainly in electrovalent compounds where

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  3. Which of the following statements is correct?

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  4. In a face centred cubic arrangement of A and B atoms whose A atoms are...

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  5. Which of the following defects, if present, lowers the density of the ...

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  6. Schottky defect is generally observed in :

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  7. The flame colours of metal ions are due to

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  8. Doping of silicon (Si) with boron (B) leads to the formation of

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  9. Density of a crystal remains unchanged as a result of :

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  10. Which of the following statement is true?

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  11. If we mix a pentavalent impurity in a crystal lattice of germanium, wh...

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  12. Which of the following has the highest value of energy gap ?

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  13. The elements commonly used for making transistors are :

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  14. How many 'nearest' and 'next nearest' neighbours respectively does sod...

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  15. The cation/anion radius ratio for a triangular arrangement of anions i...

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  16. if a metal has a bcc crystal structure, the coordination number is 8,b...

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  17. In a ccp structure, the :

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  18. The numbers of tetrahedral and octahedral holes in a ccp array of 100 ...

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  19. The size of Cl^(-) ion is 1.8Å . The size of a cation for which a chan...

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  20. Lithium forms body centred cubic structure. The length of the side of ...

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