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Correct Lewis structure is:...

Correct Lewis structure is:

A

`[:underset(..)overset(..)O-C=underset(..)overset(..)N:]^(-)`

B

`[C=C:]^(2-)`

C

`[:underset(..)overset(..)Cl-underset(..)overset(..)O:]^(-)`

D

`:overset(..)N=overset(..)O:`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct Lewis structure from the given options, we will analyze each structure step by step, focusing on the octet rule and the distribution of electrons. ### Step-by-Step Solution: 1. **Analyze the First Structure:** - The first structure shows oxygen with three lone pairs, a single bond to carbon, and carbon double bonded to nitrogen, which has three lone pairs and a negative charge. - Count the electrons around oxygen: 6 (from lone pairs) + 2 (from the bond with carbon) = 8 electrons. **Oxygen's octet is complete.** - Count the electrons around carbon: 2 (from the bond with oxygen) + 4 (from the double bond with nitrogen) = 6 electrons. **Carbon's octet is incomplete.** - **Conclusion:** This structure is incorrect because carbon does not have a complete octet. 2. **Analyze the Second Structure:** - The second structure shows carbon double bonded to another carbon, with a lone pair and a 2- charge. - Count the electrons around the first carbon: 4 (from the double bond) = 4 electrons. **This carbon's octet is incomplete.** - Count the electrons around the second carbon: 4 (from the double bond) + 2 (from the lone pair) = 6 electrons. **This carbon's octet is also incomplete.** - **Conclusion:** This structure is incorrect because both carbons do not have complete octets. 3. **Analyze the Third Structure:** - The third structure shows chlorine with 6 electrons (3 lone pairs) and oxygen with 6 electrons (3 lone pairs) and a negative charge. - Count the electrons around chlorine: 6 (from lone pairs) + 2 (from the bond with oxygen) = 8 electrons. **Chlorine's octet is complete.** - Count the electrons around oxygen: 6 (from lone pairs) + 2 (from the bond with chlorine) = 8 electrons. **Oxygen's octet is complete.** - **Conclusion:** This structure is correct because both chlorine and oxygen have complete octets. 4. **Analyze the Fourth Structure:** - The fourth structure shows nitrogen with a complete octet and oxygen also with a complete octet. - Count the electrons around nitrogen: 2 (from bonds) + 6 (from lone pairs) = 8 electrons. **Nitrogen's octet is complete.** - Count the electrons around oxygen: 6 (from lone pairs) + 2 (from the bond with nitrogen) = 8 electrons. **Oxygen's octet is complete.** - However, nitrogen in its non-bonded state has 5 electrons (3 from lone pairs and 2 from bonds), which is not possible. - **Conclusion:** This structure is incorrect because nitrogen cannot have an incomplete octet in its non-bonded state. ### Final Conclusion: The only correct Lewis structure is the third one, where both chlorine and oxygen have complete octets. ---

To determine the correct Lewis structure from the given options, we will analyze each structure step by step, focusing on the octet rule and the distribution of electrons. ### Step-by-Step Solution: 1. **Analyze the First Structure:** - The first structure shows oxygen with three lone pairs, a single bond to carbon, and carbon double bonded to nitrogen, which has three lone pairs and a negative charge. - Count the electrons around oxygen: 6 (from lone pairs) + 2 (from the bond with carbon) = 8 electrons. **Oxygen's octet is complete.** - Count the electrons around carbon: 2 (from the bond with oxygen) + 4 (from the double bond with nitrogen) = 6 electrons. **Carbon's octet is incomplete.** ...
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VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-Level - 1 (JEE Main)
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  2. In terms of polar character, which of the following order is correct ?

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  3. Correct Lewis structure is:

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  4. Which one of the following compounds has bond angle close to 90^@ ?

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  5. Pick out among the following, species isoelectronic with CO(2).

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  6. The shape of NH2^(-) is like that of

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  7. The benzene molecule is :

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  8. Which of the following ions has an (18 + 2) electronic configuration ?

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  9. Which of the following ions has a pseudo-inert-gas configuration?

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  10. Which of the following elements can form both ionic and covalent bonds...

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  11. The total number of covalent bonds present in the NO(2)^(+) ion is :

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  12. Which set contain no ionic species?

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  13. Which of the following has zero dipole moment?

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  14. Which are non-polar molecules? I. NCl(3) " "II. SO(3)" ...

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  15. Which of the following ions has the maximum polarising power?

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  16. All the following molecules are polar except one

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  17. Which of the following has the highest percentage of ionic character i...

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  18. Which of the following is non-polar but contains polar bonds?

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  19. The N(2)H(4) molecule contains :

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  20. Which statement is not correct about NO(2) ?

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