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Which statement is not correct about NO(...

Which statement is not correct about `NO_(2)` ?

A

It is paramagnetic

B

It forms dimer and paramanetism is lost

C

It has one coordinate bond

D

It has nitrogen oxygen triple bond

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not correct about \( NO_2 \), we can analyze the properties and bonding of the molecule step by step. ### Step 1: Understanding the Structure of \( NO_2 \) - **Valence Electrons**: Nitrogen has 5 valence electrons, and each oxygen has 6 valence electrons. Therefore, in \( NO_2 \): - Nitrogen contributes 5 electrons. - Each oxygen contributes 6 electrons, totaling 12 from both oxygens. - Total valence electrons = \( 5 + 12 = 17 \) electrons. ### Step 2: Drawing the Lewis Structure - **Bonding**: In \( NO_2 \), nitrogen forms: - One double bond with one oxygen (4 electrons). - One single bond with the other oxygen (2 electrons). - This accounts for 6 electrons used in bonding. - **Lone Pairs**: The remaining electrons (11 electrons) are distributed as follows: - Each oxygen has 3 lone pairs (6 electrons) and one oxygen has one unpaired electron. - The nitrogen has one unpaired electron. ### Step 3: Determining the Electron Count - **Total Electrons**: The total number of electrons in \( NO_2 \) is 17, which is an odd number. This confirms that \( NO_2 \) is an odd-electron species. ### Step 4: Paramagnetism - **Unpaired Electrons**: Since \( NO_2 \) has an unpaired electron, it is paramagnetic. This means it can be attracted to a magnetic field. ### Step 5: Dimerization - **Dimerization**: \( NO_2 \) can dimerize to form \( N_2O_4 \). In this process, the unpaired electrons pair up, resulting in a diamagnetic molecule. ### Step 6: Evaluating the Statements Now, let's evaluate the statements provided in the question: 1. **It is paramagnetic** - This is correct. 2. **It forms a dimer and loses paramagnetism** - This is also correct. 3. **It has one coordinate bond** - This is correct as well. 4. **It has a nitrogen-oxygen triple bond** - This is incorrect. The bonding in \( NO_2 \) consists of one double bond and one single bond, not a triple bond. ### Conclusion The statement that is not correct about \( NO_2 \) is that it has a nitrogen-oxygen triple bond. ---

To determine which statement is not correct about \( NO_2 \), we can analyze the properties and bonding of the molecule step by step. ### Step 1: Understanding the Structure of \( NO_2 \) - **Valence Electrons**: Nitrogen has 5 valence electrons, and each oxygen has 6 valence electrons. Therefore, in \( NO_2 \): - Nitrogen contributes 5 electrons. - Each oxygen contributes 6 electrons, totaling 12 from both oxygens. - Total valence electrons = \( 5 + 12 = 17 \) electrons. ...
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