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Which of the following will have the mol...

Which of the following will have the molecular shape of a trigonal bipyramid?

A

`PF_(3)Cl_(2)`

B

`IF_(5)`

C

`BrF_(5)`

D

`SbF_(5)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds has a molecular shape of trigonal bipyramidal, we need to analyze the number of bond pairs and lone pairs around the central atom in each compound. The trigonal bipyramidal shape occurs when there are five bond pairs and no lone pairs. ### Step-by-Step Solution: 1. **Understand the Trigonal Bipyramidal Shape**: - A trigonal bipyramidal molecular shape has a central atom bonded to five other atoms, with bond angles of 120° in the equatorial plane and 90° between the axial and equatorial positions. 2. **Identify the Compounds**: - The options given are PF3Cl2, IF5, BrF5, and SbF5-2. 3. **Analyze Each Compound**: - **Option A: PF3Cl2**: - Phosphorus (P) has 5 valence electrons. It forms 5 bonds (3 with F and 2 with Cl) and has 0 lone pairs. - Bond pairs = 5, Lone pairs = 0. - This fits the criteria for a trigonal bipyramidal shape. - **Option B: IF5**: - Iodine (I) has 7 valence electrons. It forms 5 bonds with F and has 1 lone pair. - Bond pairs = 5, Lone pairs = 1. - This results in a square pyramidal shape, not trigonal bipyramidal. - **Option C: BrF5**: - Bromine (Br) also has 7 valence electrons. It forms 5 bonds with F and has 1 lone pair. - Bond pairs = 5, Lone pairs = 1. - This also results in a square pyramidal shape, not trigonal bipyramidal. - **Option D: SbF5-2**: - Antimony (Sb) has 5 valence electrons. With a -2 charge, it effectively has 7 electrons. It forms 5 bonds with F and has 2 lone pairs. - Bond pairs = 5, Lone pairs = 2. - This leads to a different geometry, not trigonal bipyramidal. 4. **Conclusion**: - The only compound that has a trigonal bipyramidal shape is **PF3Cl2**. ### Final Answer: **PF3Cl2** has a molecular shape of trigonal bipyramidal.

To determine which of the given compounds has a molecular shape of trigonal bipyramidal, we need to analyze the number of bond pairs and lone pairs around the central atom in each compound. The trigonal bipyramidal shape occurs when there are five bond pairs and no lone pairs. ### Step-by-Step Solution: 1. **Understand the Trigonal Bipyramidal Shape**: - A trigonal bipyramidal molecular shape has a central atom bonded to five other atoms, with bond angles of 120° in the equatorial plane and 90° between the axial and equatorial positions. 2. **Identify the Compounds**: ...
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VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-Level - 1 (JEE Main)
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  2. In the solid state, N(2)O(5) exists as [NO(2)]^(+)[NO(3)]^(-) . The h...

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  4. Molecular shapes of SF(4), CF(4), XeF(4) are

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  5. The strength of bonds by overlapping of atomic orbitals is in order

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  6. Which of the following molecules or ions is not linear?

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  7. In carbon-hydrogen-oxygen compounds :

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  8. The shapes of XeO(2)F(2) molecule is

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  9. Which of the following ions has resonating structures?

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  10. Covalency of carbon in the CO molecule is three because

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  11. Which has maximum number of lone pair of electrons present on central ...

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  12. The nitrogen atom in NH(3), NH(2)^(-) and NH(4)^(+) are all surrounde...

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  13. Which of the following has the highest boiling point?

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  14. The correct order of dipole moments of HF, H(2)S and H(2)O is :

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  15. The correct order of increasing bond length of C-H, C-O, C - C and C =...

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  16. Which of the following compound or ion is planar?

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  17. Explain why PCl(5) is trigonal bipyramidal whereas IF(5) is square pyr...

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  18. In diborane (B(2)H(6)), the bond formed between B and B is called :

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  19. Which of the following pairs have identical value of bond order?

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  20. In Be(2) the bond order is

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