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The strength of bonds by overlapping of ...

The strength of bonds by overlapping of atomic orbitals is in order

A

`2s-2s gt 2s-2p gt 2p-2p`

B

`2s-2p lt 2s-2s lt 2p-2p`

C

`2s-2s lt 2s-2p lt 2p-2p`

D

`2p-2p lt 2s-2s lt 2s-2p`

Text Solution

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The correct Answer is:
To determine the strength of bonds formed by the overlapping of atomic orbitals, we can analyze the types of overlaps and their corresponding strengths. The order of bond strength can be derived from the directional character of the orbitals involved in the bonding. ### Step-by-Step Solution: 1. **Understanding Bond Types**: - Bonds can be formed by the overlapping of different types of atomic orbitals: s, p, and hybrid orbitals (like sp). - Sigma (σ) bonds are formed by the head-on overlap of orbitals. 2. **Analyzing Orbital Overlaps**: - **s-s Overlap**: This involves two s orbitals. The s orbital is spherical, which means it has less directional character. Therefore, the overlap is less effective. - **p-p Overlap**: This involves two p orbitals. P orbitals have a more directional character due to their shape, allowing for a stronger head-on overlap compared to s orbitals. - **s-p Overlap**: This involves one s orbital and one p orbital. The overlap is better than s-s but not as strong as p-p due to the directional nature of p orbitals. 3. **Comparing Strengths**: - Based on the analysis: - p-p overlap (pp) is stronger than s-p overlap (sp). - s-p overlap (sp) is stronger than s-s overlap (ss). - Therefore, the order of bond strength from strongest to weakest is: - pp > sp > ss 4. **Conclusion**: - The correct order of bond strength based on the overlapping of atomic orbitals is: - pp > sp > ss ### Final Answer: The strength of bonds by overlapping of atomic orbitals is in the order: **pp > sp > ss**.

To determine the strength of bonds formed by the overlapping of atomic orbitals, we can analyze the types of overlaps and their corresponding strengths. The order of bond strength can be derived from the directional character of the orbitals involved in the bonding. ### Step-by-Step Solution: 1. **Understanding Bond Types**: - Bonds can be formed by the overlapping of different types of atomic orbitals: s, p, and hybrid orbitals (like sp). - Sigma (σ) bonds are formed by the head-on overlap of orbitals. ...
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The strength of bonds formed by overlapping of atomic orbitals is in the order .

The strength of bonds formed by overlapping of 2s-2s, 2p-2p and 2p-2s follows the order

Knowledge Check

  • Assertion :-The o-bond is stronger as compared to a pi -bond. Reason :-The axial overlapping of atomic orbitals is much more as compared to their sidewise overlapping.

    A
    If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion
    B
    If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.
    C
    If Assertion is CORRECT but Reason is INCORRECT.
    D
    If Assertion is INCORRECT but Reason is CORRECT.
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    A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. The strength of bonds formed by 2s-2s,2p-2p and 2p-2s overlap has the order :

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