Home
Class 12
CHEMISTRY
The strength of bonds by overlapping of ...

The strength of bonds by overlapping of atomic orbitals is in order

A

`2s-2s gt 2s-2p gt 2p-2p`

B

`2s-2p lt 2s-2s lt 2p-2p`

C

`2s-2s lt 2s-2p lt 2p-2p`

D

`2p-2p lt 2s-2s lt 2s-2p`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strength of bonds formed by the overlapping of atomic orbitals, we can analyze the types of overlaps and their corresponding strengths. The order of bond strength can be derived from the directional character of the orbitals involved in the bonding. ### Step-by-Step Solution: 1. **Understanding Bond Types**: - Bonds can be formed by the overlapping of different types of atomic orbitals: s, p, and hybrid orbitals (like sp). - Sigma (σ) bonds are formed by the head-on overlap of orbitals. 2. **Analyzing Orbital Overlaps**: - **s-s Overlap**: This involves two s orbitals. The s orbital is spherical, which means it has less directional character. Therefore, the overlap is less effective. - **p-p Overlap**: This involves two p orbitals. P orbitals have a more directional character due to their shape, allowing for a stronger head-on overlap compared to s orbitals. - **s-p Overlap**: This involves one s orbital and one p orbital. The overlap is better than s-s but not as strong as p-p due to the directional nature of p orbitals. 3. **Comparing Strengths**: - Based on the analysis: - p-p overlap (pp) is stronger than s-p overlap (sp). - s-p overlap (sp) is stronger than s-s overlap (ss). - Therefore, the order of bond strength from strongest to weakest is: - pp > sp > ss 4. **Conclusion**: - The correct order of bond strength based on the overlapping of atomic orbitals is: - pp > sp > ss ### Final Answer: The strength of bonds by overlapping of atomic orbitals is in the order: **pp > sp > ss**.

To determine the strength of bonds formed by the overlapping of atomic orbitals, we can analyze the types of overlaps and their corresponding strengths. The order of bond strength can be derived from the directional character of the orbitals involved in the bonding. ### Step-by-Step Solution: 1. **Understanding Bond Types**: - Bonds can be formed by the overlapping of different types of atomic orbitals: s, p, and hybrid orbitals (like sp). - Sigma (σ) bonds are formed by the head-on overlap of orbitals. ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise Level - 2 (JEE Advanced)|50 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Main (Numerical Value Questions)|15 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise Level - 0 (Long Answer Type)|4 Videos
  • CHEMICAL BONDING & MOLECULAR STRUCTURE

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-L|9 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - G|10 Videos

Similar Questions

Explore conceptually related problems

The strength of bonds formed by overlapping of atomic orbitals is in the order .

The strength of bonds formed by overlapping of 2s-2s, 2p-2p and 2p-2s follows the order

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. The strength of bonds formed by 2s-2s,2p-2p and 2p-2s overlap has the order :

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. The strength of bonds formed by 2s-2s,2p-2p and 2p-2s overlap has the order :

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. Compound having maximum bond angle is :

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. Compound having maximum bond angle is :

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. The correct order of increasing C-O bond length of CO,CO_(3)^(2-),CO_(2) is :

Assertion :-The o-bond is stronger as compared to a pi -bond. Reason :-The axial overlapping of atomic orbitals is much more as compared to their sidewise overlapping.

What do you understand by overlapping of orbitals? Discuss the overlapping of p-orbitals.

Assuming the bond direction to the z-axis, which of the overlapping of atomic orbitals of two atom (A) and (B) will result in bonding ? (I) s-orbital of A and p_(x) orbital of B (II) s-orbital of A and p_(z) orbital of B (III) p_(y) -orbital of A and p_(z) orbital of B (IV) s-orbital of both (A) and (B)

VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-Level - 1 (JEE Main)
  1. Which of the following will have the molecular shape of a trigonal bip...

    Text Solution

    |

  2. Molecular shapes of SF(4), CF(4), XeF(4) are

    Text Solution

    |

  3. The strength of bonds by overlapping of atomic orbitals is in order

    Text Solution

    |

  4. Which of the following molecules or ions is not linear?

    Text Solution

    |

  5. In carbon-hydrogen-oxygen compounds :

    Text Solution

    |

  6. The shapes of XeO(2)F(2) molecule is

    Text Solution

    |

  7. Which of the following ions has resonating structures?

    Text Solution

    |

  8. Covalency of carbon in the CO molecule is three because

    Text Solution

    |

  9. Which has maximum number of lone pair of electrons present on central ...

    Text Solution

    |

  10. The nitrogen atom in NH(3), NH(2)^(-) and NH(4)^(+) are all surrounde...

    Text Solution

    |

  11. Which of the following has the highest boiling point?

    Text Solution

    |

  12. The correct order of dipole moments of HF, H(2)S and H(2)O is :

    Text Solution

    |

  13. The correct order of increasing bond length of C-H, C-O, C - C and C =...

    Text Solution

    |

  14. Which of the following compound or ion is planar?

    Text Solution

    |

  15. Explain why PCl(5) is trigonal bipyramidal whereas IF(5) is square pyr...

    Text Solution

    |

  16. In diborane (B(2)H(6)), the bond formed between B and B is called :

    Text Solution

    |

  17. Which of the following pairs have identical value of bond order?

    Text Solution

    |

  18. In Be(2) the bond order is

    Text Solution

    |

  19. The number of anti bonding electrons in N(2) is

    Text Solution

    |

  20. A simplified applified of MO theory to the hypotheritical molecule OF ...

    Text Solution

    |