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In ClF(3), lone pair of electrons is pre...

In `ClF_(3)`, lone pair of electrons is present at equatorial position to minimize :

A

Lone pair –lone pair repulsion only

B

Lone pair-bond pair repulsion mainly

C

Lone pair –lone pair and lone pair-bond pair repulsion only

D

Lone pair-lone pair and bond pair-bond pair repulsion only

Text Solution

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The correct Answer is:
To solve the question regarding the presence of lone pairs in the equatorial position in ClF₃, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Molecular Geometry**: - ClF₃ (Chlorine trifluoride) is an interhalogen compound. The central atom is chlorine (Cl), which is bonded to three fluorine (F) atoms. 2. **Determine the Number of Valence Electrons**: - Chlorine has 7 valence electrons, and each fluorine has 7 valence electrons. Therefore, the total number of valence electrons in ClF₃ is: \[ 7 \text{ (from Cl)} + 3 \times 7 \text{ (from F)} = 28 \text{ valence electrons} \] 3. **Account for Bonding and Lone Pairs**: - In ClF₃, there are three Cl-F bonds, which use up 6 valence electrons (2 electrons per bond). This leaves us with: \[ 28 - 6 = 22 \text{ electrons} \] - Since each lone pair consists of 2 electrons, the remaining 22 electrons can be used to form lone pairs. Chlorine has 2 lone pairs remaining after forming three bonds. 4. **Determine the Arrangement of Lone Pairs and Bonding Pairs**: - The molecular geometry of ClF₃ is based on the VSEPR theory. The presence of 3 bonding pairs and 2 lone pairs leads to a trigonal bipyramidal arrangement. - To minimize repulsion, the lone pairs will occupy the equatorial positions, while the bonding pairs will occupy the axial positions. 5. **Minimize Repulsion**: - Lone pairs are more repulsive than bonding pairs. By placing the lone pairs in the equatorial positions, we minimize the lone pair-lone pair and lone pair-bond pair repulsions. This arrangement leads to a T-shaped molecular geometry. 6. **Conclusion**: - Therefore, in ClF₃, the lone pairs are located at the equatorial positions to minimize repulsion between lone pairs and bonding pairs. ### Final Answer: In ClF₃, the lone pair of electrons is present at the equatorial position to minimize lone pair-lone pair and lone pair-bond pair repulsion.

To solve the question regarding the presence of lone pairs in the equatorial position in ClF₃, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Molecular Geometry**: - ClF₃ (Chlorine trifluoride) is an interhalogen compound. The central atom is chlorine (Cl), which is bonded to three fluorine (F) atoms. 2. **Determine the Number of Valence Electrons**: ...
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