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In the conversion of N(2) into N(2)^(+)...

In the conversion of `N_(2)` into `N_(2)^(+)` the electron will be lost from which of the following molecular orbital ?

A

`sigma^(*)2p_(z)`

B

`sigma2p_(z)`

C

`pi 2p_(x)`

D

`pi^(**)2p_(x)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine from which molecular orbital an electron is lost when converting \( N_2 \) into \( N_2^+ \), we can follow these steps: ### Step 1: Determine the Total Number of Electrons in \( N_2 \) - Each nitrogen atom has 7 electrons, so for \( N_2 \): \[ \text{Total electrons} = 7 \times 2 = 14 \] ### Step 2: Write the Molecular Orbital Electronic Configuration for \( N_2 \) - The molecular orbital configuration for \( N_2 \) with 14 electrons is: \[ \sigma 1s^2, \sigma^* 1s^2, \sigma 2s^2, \sigma^* 2s^2, \pi 2p_x^2, \pi 2p_y^2, \sigma 2p_z^2 \] - The configuration can be summarized as: \[ \sigma 1s^2, \sigma^* 1s^2, \sigma 2s^2, \sigma^* 2s^2, \pi 2p_x^2, \pi 2p_y^2, \sigma 2p_z^2 \] ### Step 3: Identify the Highest Energy Molecular Orbital - The order of energy levels for the molecular orbitals in \( N_2 \) is: \[ \sigma 1s < \sigma^* 1s < \sigma 2s < \sigma^* 2s < \pi 2p_x = \pi 2p_y < \sigma 2p_z \] - The highest energy orbital filled in \( N_2 \) is \( \sigma 2p_z \). ### Step 4: Remove One Electron to Form \( N_2^+ \) - When converting \( N_2 \) to \( N_2^+ \), we remove one electron from the highest energy molecular orbital, which is \( \sigma 2p_z \). ### Conclusion - The electron will be lost from the \( \sigma 2p_z \) molecular orbital when converting \( N_2 \) into \( N_2^+ \). ### Final Answer The electron will be lost from the \( \sigma 2p_z \) molecular orbital. ---

To determine from which molecular orbital an electron is lost when converting \( N_2 \) into \( N_2^+ \), we can follow these steps: ### Step 1: Determine the Total Number of Electrons in \( N_2 \) - Each nitrogen atom has 7 electrons, so for \( N_2 \): \[ \text{Total electrons} = 7 \times 2 = 14 \] ...
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