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The shape of "XeOF"(2) on the basis of V...

The shape of `"XeOF"_(2)` on the basis of VSEPR theory is

A

trigonal bipyramidal

B

square pyramidal

C

octahedral

D

pentagonal planar

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The correct Answer is:
To determine the shape of \( \text{XeOF}_2 \) based on VSEPR theory, we will follow these steps: ### Step 1: Determine the Valence Electrons Xenon (Xe) is in group 18 and has 8 valence electrons. Oxygen (O) is in group 16 and has 6 valence electrons. Each fluorine (F) atom is in group 17 and has 7 valence electrons. Calculating the total valence electrons: - Xe: 8 - O: 6 - F: 7 (for 2 F atoms, we have \( 7 \times 2 = 14 \)) Total valence electrons = \( 8 + 6 + 14 = 28 \) electrons. ### Step 2: Determine the Bonds and Lone Pairs In \( \text{XeOF}_2 \): - Xenon forms a double bond with oxygen (using 4 electrons). - Xenon forms single bonds with two fluorine atoms (using 2 electrons for each bond, totaling 4 electrons). Thus, the bonds consume: - 4 electrons (double bond with O) - 4 electrons (two single bonds with F) Total electrons used for bonding = \( 4 + 4 = 8 \) electrons. Remaining electrons = \( 28 - 8 = 20 \) electrons. ### Step 3: Calculate Lone Pairs on Xenon The remaining 20 electrons will be used as lone pairs on xenon. Each lone pair consists of 2 electrons, so: - Number of lone pairs = \( \frac{20}{2} = 10 \) lone pairs. However, we need to consider the actual arrangement. ### Step 4: Count the Bonding Regions - 1 double bond with oxygen = 1 bonding region - 2 single bonds with fluorine = 2 bonding regions Total bonding regions = \( 1 + 2 = 3 \). ### Step 5: Determine the Lone Pairs Since we have 3 bonding regions, we can calculate the number of lone pairs: - Total valence electrons = 8 (Xe) + 6 (O) + 14 (F) = 28 - Electrons used in bonds = 8 - Remaining electrons = 20 - Each lone pair consists of 2 electrons, so the number of lone pairs on Xe = \( \frac{20}{2} = 10 \). ### Step 6: Hybridization The total number of regions (bonding + lone pairs) around xenon is: - 3 bonding regions + 2 lone pairs = 5 regions. The hybridization corresponding to 5 regions is \( sp^3d \). ### Step 7: Determine the Geometry The geometry of \( sp^3d \) is trigonal bipyramidal. However, the presence of lone pairs affects the shape: - The two lone pairs will occupy the equatorial positions to minimize repulsion. ### Step 8: Final Shape With two lone pairs in the equatorial position and three bonding pairs (one double bond with oxygen and two single bonds with fluorine), the resulting molecular shape is T-shaped. ### Conclusion The shape of \( \text{XeOF}_2 \) based on VSEPR theory is T-shaped. ---

To determine the shape of \( \text{XeOF}_2 \) based on VSEPR theory, we will follow these steps: ### Step 1: Determine the Valence Electrons Xenon (Xe) is in group 18 and has 8 valence electrons. Oxygen (O) is in group 16 and has 6 valence electrons. Each fluorine (F) atom is in group 17 and has 7 valence electrons. Calculating the total valence electrons: - Xe: 8 - O: 6 ...
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VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-JEE Main (Archive)
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