Home
Class 12
CHEMISTRY
Molecule AB has a bond length of 1.617Å ...

Molecule AB has a bond length of `1.617Å` and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is :
`(e_(0)=4.802xx10^(-10)"esu")`

A

0

B

0.05

C

0.5

D

`1.0`

Text Solution

AI Generated Solution

The correct Answer is:
To find the fractional charge on each atom in the molecule AB, we will follow these steps: ### Step 1: Convert the bond length to centimeters The given bond length is \(1.617 \, \text{Å}\). We need to convert this to centimeters. \[ 1 \, \text{Å} = 10^{-10} \, \text{m} \quad \text{and} \quad 1 \, \text{m} = 100 \, \text{cm} \] Thus, \[ 1.617 \, \text{Å} = 1.617 \times 10^{-10} \, \text{m} = 1.617 \times 10^{-8} \, \text{cm} \] ### Step 2: Convert the dipole moment to esu cm The given dipole moment is \(0.38 \, \text{D}\). We need to convert this to esu cm. \[ 1 \, \text{D} = 1 \times 10^{-18} \, \text{esu cm} \] Thus, \[ 0.38 \, \text{D} = 0.38 \times 10^{-18} \, \text{esu cm} \] ### Step 3: Use the formula for dipole moment The dipole moment (\(\mu\)) is related to the charge (\(q\)) and the distance (\(L\)) by the formula: \[ \mu = q \times L \] We can rearrange this to find the charge: \[ q = \frac{\mu}{L} \] ### Step 4: Substitute the values Substituting the values we have: \[ q = \frac{0.38 \times 10^{-18} \, \text{esu cm}}{1.617 \times 10^{-8} \, \text{cm}} \] ### Step 5: Calculate the charge Calculating the charge: \[ q = \frac{0.38 \times 10^{-18}}{1.617 \times 10^{-8}} = 0.235 \times 10^{-10} \, \text{esu} \] ### Step 6: Calculate the fractional charge The absolute value of the charge on each atom (\(e_0\)) is given as \(4.802 \times 10^{-10} \, \text{esu}\). The fractional charge (\(f\)) is given by: \[ f = \frac{q}{e_0} \] Substituting the values: \[ f = \frac{0.235 \times 10^{-10}}{4.802 \times 10^{-10}} \] ### Step 7: Perform the division Calculating the fractional charge: \[ f = 0.05 \] ### Final Answer The fractional charge on each atom (absolute magnitude) is \(0.05\). ---

To find the fractional charge on each atom in the molecule AB, we will follow these steps: ### Step 1: Convert the bond length to centimeters The given bond length is \(1.617 \, \text{Å}\). We need to convert this to centimeters. \[ 1 \, \text{Å} = 10^{-10} \, \text{m} \quad \text{and} \quad 1 \, \text{m} = 100 \, \text{cm} \] ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Main (Numerical Value Questions)|15 Videos
  • CHEMICAL BONDING & MOLECULAR STRUCTURE

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-L|9 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - G|10 Videos

Similar Questions

Explore conceptually related problems

Diatomic molecule has a dipole moment of 1.2D If its bond 1.0 Å what fraction of an electronic charge exists on each atom ? .

The bond length of H-X molecule is 1. 2 Å and the dipole moment of the molecule is 1.1D. Calculate % inonic character of the bond.

An HCl molecule has a dipole moment of 3.4xx 10(-30) Cm . Assuming that equal and opposite charges lie on the two . atoms to froma dipole, what is the magnitude of this . charge? The separation between the two atoms of HCl is . 1.0x10(-10)m .

A diatomic molecule has dipole moment of 1.2 D . If the bond distance is 1 Å what parcentage of covalent in the molecule is

Calculate the percentage of covalent character of HX having bond length = 1.62 Å and observed dipole moment = 0.39 D.

In a carbon monoxide molecule, the carbon and the oxygen atoms are separted by a distance 1.12 xx 10^(-10) m. The distance of the centre of mass from the carbon atom is A. 0.64 xx 10^(-10)m B. 0.56xx10^(-6) m C. 0.51 xx 10^(-10) m D. 0.48 xx 10^(-10) m

What is the magnitude of a point charge due to which the electric field 30cm away the magnitude 2 ? [1//4 pi epsilon_(0)=9xx10^(9)Nm^(2)//C^(2)]

If the dipole moment of AB molecule is given by 1.2 D and A - B the bond length is 1­Å then % ionic character of the bond is [Given : 1 debye =10^(-18) esu. Cm]

Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. A diatomic molecule has a dipole moment of 1.2D. If the bond length is 1.0times10^(-8) cm, what fraction of charge does exist each atom?

Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. Which is a polar molecule?

VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-JEE Main (Archive)
  1. The intermolecular interaction that is dependent on the inverse cube o...

    Text Solution

    |

  2. The shape of "XeOF"(2) on the basis of VSEPR theory is

    Text Solution

    |

  3. Molecule AB has a bond length of 1.617Å and a dipole moment of 0.38 D....

    Text Solution

    |

  4. The species in which the N atom is in a state of sp hybridization is :

    Text Solution

    |

  5. After understanding the assertion and reason, choose the correct optio...

    Text Solution

    |

  6. Choose the incorrect formula out of the four compounds for an element ...

    Text Solution

    |

  7. The group of molecules having identical shape is:

    Text Solution

    |

  8. The bond angle H-X-H is the greatest in teh compound :

    Text Solution

    |

  9. Which of the following species is not paramagnetic?

    Text Solution

    |

  10. The group having isoelectronic species is

    Text Solution

    |

  11. Which of the following is paramagnetic ?

    Text Solution

    |

  12. The group having triangular planar structures is :

    Text Solution

    |

  13. Total number of lone pair of electrons in I(3)^(-) ion is

    Text Solution

    |

  14. Which of the following compounds contain(s) no covalent bond(s)? K...

    Text Solution

    |

  15. According to molecular orbital theory, which of the following will not...

    Text Solution

    |

  16. During the change of O(2) to O(2)^(-), the incoming electron goes to t...

    Text Solution

    |

  17. The oxoacid of sulphur that does not contain bond between sulphur atom...

    Text Solution

    |

  18. Among the following, the molecule expected to be stabilized by anion f...

    Text Solution

    |

  19. The basic structural unit of feldspar, zeolites, mica, and asbestos is...

    Text Solution

    |

  20. The correct statement among the following is:

    Text Solution

    |