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During the change of O(2) to O(2)^(-), t...

During the change of `O_(2)` to `O_(2)^(-)`, the incoming electron goes to the orbital:

A

`pi 2p_(y)`

B

`sigma**2p_(z)`

C

`pi ** 2p_(x)`

D

`pi 2p_(x)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the change of \( O_2 \) to \( O_2^- \) and the orbital to which the incoming electron goes, we can follow these steps: ### Step-by-Step Solution: 1. **Determine the Molecular Orbital Configuration of \( O_2 \)**: - Oxygen (\( O \)) has an atomic number of 8, which means each oxygen atom contributes 8 electrons. Therefore, \( O_2 \) has a total of \( 8 + 8 = 16 \) electrons. - The molecular orbital configuration for \( O_2 \) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \sigma_{2p_z}^2 \pi_{2p_x}^2 \pi_{2p_y}^2 \pi_{2p_x}^*^1 \pi_{2p_y}^*^1 \] - This configuration indicates that the \( O_2 \) molecule has two electrons in the \( \pi^* \) orbitals. 2. **Identify the Lowest Unoccupied Molecular Orbital (LUMO)**: - In the configuration above, the \( \pi^* \) orbitals (\( \pi_{2p_x}^* \) and \( \pi_{2p_y}^* \)) are the lowest unoccupied molecular orbitals (LUMOs). - Since both \( \pi_{2p_x}^* \) and \( \pi_{2p_y}^* \) are singly occupied, they can accommodate one more electron. 3. **Determine the Orbital for Incoming Electron**: - When \( O_2 \) gains an electron to become \( O_2^- \), this incoming electron will occupy one of the \( \pi^* \) orbitals. - The incoming electron will pair with one of the existing electrons in the \( \pi_{2p_x}^* \) or \( \pi_{2p_y}^* \) orbital. 4. **Final Answer**: - The incoming electron goes to the \( \pi_{2p_x}^* \) orbital (or equivalently \( \pi_{2p_y}^* \)), but typically we refer to \( \pi_{2p_x}^* \) in such contexts. - Therefore, the correct answer is that the incoming electron goes to the \( \pi^*_{2p_x} \) orbital.

To solve the question regarding the change of \( O_2 \) to \( O_2^- \) and the orbital to which the incoming electron goes, we can follow these steps: ### Step-by-Step Solution: 1. **Determine the Molecular Orbital Configuration of \( O_2 \)**: - Oxygen (\( O \)) has an atomic number of 8, which means each oxygen atom contributes 8 electrons. Therefore, \( O_2 \) has a total of \( 8 + 8 = 16 \) electrons. - The molecular orbital configuration for \( O_2 \) is: \[ ...
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