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The correct statement among the followin...

The correct statement among the following is:

A

`(SiH_(3))_(3)N` is planar and less basic than `(CH_(3))_(3)N`

B

`(SiH_(3))_(3)N` is planar and more basic than `(CH_(3))_(3)N`

C

`(SiH_(3))_(3)N` is pyramidal and less basic than `(CH_(3))_(3)N`

D

`(SiH_(3))_(3)N` is pyramidal and more basic than `(CH_(3))_(3)N`

Text Solution

Verified by Experts

The correct Answer is:
A

Due to formation of `p pi-d pi` back bonding. `N(SiH_(3))` is `Sp^(2)` hybridized. Hence it is planar and less basic than `N(CH_(3))_(3)`.
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VMC MODULES ENGLISH-CHEMICAL BONDING-I & II-JEE Main (Archive)
  1. Which of the following species is not paramagnetic?

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  2. The group having isoelectronic species is

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  3. Which of the following is paramagnetic ?

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  4. The group having triangular planar structures is :

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  5. Total number of lone pair of electrons in I(3)^(-) ion is

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  6. Which of the following compounds contain(s) no covalent bond(s)? K...

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  7. According to molecular orbital theory, which of the following will not...

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  8. During the change of O(2) to O(2)^(-), the incoming electron goes to t...

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  9. The oxoacid of sulphur that does not contain bond between sulphur atom...

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  10. Among the following, the molecule expected to be stabilized by anion f...

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  11. The basic structural unit of feldspar, zeolites, mica, and asbestos is...

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  12. The correct statement among the following is:

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  13. Among the following species, the diamagnetic molecule is :

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  14. The ion that has sp ^ 3 d ^ 2 hybridization for the central ...

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  15. Among the following molecules/ions C(2)^(2-),N(2)^(2-),O(2)^(2-),O(2) ...

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  16. The correct statement about ICl(5) and ICl(4)^(-) is

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  17. According to molecular orbital theory, which of the following is true ...

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  18. In which of the following processes, the bond order has increased and ...

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  19. Two pi and half sigma bonds are present in:

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  20. The type of hybridisation and number of lone pair(s) of electrons of X...

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