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The enthalpy of the reaction H(2)(g)+(...

The enthalpy of the reaction
`H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(g)` is `DeltaH_(1)` and that of `H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(l)` is `DeltaH_(2)`. Then

A

`Delta H_1 lt Delta H_2`

B

`Delta H_1 + Delta H_2 = 0`

C

`Delta H_1 gt Delta H_2`

D

`Delta H_1 = Delta H_2`

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The correct Answer is:
To solve the problem, we need to analyze the two reactions given and their corresponding enthalpy changes, \(\Delta H_1\) and \(\Delta H_2\). ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(g) \quad \text{(Enthalpy change = } \Delta H_1\text{)} \] - The second reaction is: \[ H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(l) \quad \text{(Enthalpy change = } \Delta H_2\text{)} \] 2. **Understanding the Nature of the Reactions**: - The first reaction produces water in the gaseous state (steam), while the second reaction produces water in the liquid state. - The transition from gas to liquid (condensation) is an exothermic process, meaning it releases heat. 3. **Comparing the Enthalpy Changes**: - In the first reaction, energy is absorbed to form gaseous water. Thus, \(\Delta H_1\) is positive. - In the second reaction, energy is released when gaseous water condenses into liquid water. Thus, \(\Delta H_2\) is negative. 4. **Relating \(\Delta H_1\) and \(\Delta H_2\)**: - Since condensation releases energy, the enthalpy change for the condensation process (\(\Delta H_2\)) will be less than that for the formation of gaseous water (\(\Delta H_1\)). - Therefore, we can conclude: \[ \Delta H_2 < \Delta H_1 \] - This implies that \(\Delta H_2\) is more negative (or less positive) than \(\Delta H_1\). 5. **Final Conclusion**: - The correct relationship between the two enthalpy changes is: \[ \Delta H_2 < \Delta H_1 \]

To solve the problem, we need to analyze the two reactions given and their corresponding enthalpy changes, \(\Delta H_1\) and \(\Delta H_2\). ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(g) \quad \text{(Enthalpy change = } \Delta H_1\text{)} ...
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