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A hypothetical reaction Ato2B, proceeds ...

A hypothetical reaction `Ato2B`, proceeds through following sequence of steps
(i) `A to C,DeltaH=q`
(ii) `C to D,DeltaH=v`
(iii) `(1)/(2)D to B,DeltaH=x`
Then, the heat of reaction is

A

`q - v + 2x`

B

`q + v - 2x`

C

`q + v + 2x`

D

`q + 2v - 2x`

Text Solution

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The correct Answer is:
To find the heat of reaction for the hypothetical reaction \( A \to 2B \) that proceeds through the given steps, we can apply Hess's law. Here’s a step-by-step solution: ### Step 1: Understand the Reaction Steps We have three steps with their respective enthalpy changes: 1. \( A \to C \), with \(\Delta H = q\) 2. \( C \to D \), with \(\Delta H = v\) 3. \( \frac{1}{2}D \to B \), with \(\Delta H = x\) ### Step 2: Write the Overall Reaction We need to combine these steps to find the overall reaction \( A \to 2B \). ### Step 3: Modify the Third Step Since the third step produces only \( B \) from \( \frac{1}{2}D \), we need to multiply this step by 2 to produce 2 moles of \( B \): - \( D \to 2B \) will have an enthalpy change of \( 2x \). ### Step 4: Combine the Reactions Now we can combine the three steps: 1. \( A \to C \) (enthalpy change = \( q \)) 2. \( C \to D \) (enthalpy change = \( v \)) 3. \( D \to 2B \) (enthalpy change = \( 2x \)) ### Step 5: Write the Overall Enthalpy Change According to Hess's law, the total enthalpy change for the overall reaction is the sum of the enthalpy changes of the individual steps: \[ \Delta H_{\text{net}} = q + v + 2x \] ### Conclusion Thus, the heat of reaction for \( A \to 2B \) is: \[ \Delta H = q + v + 2x \]

To find the heat of reaction for the hypothetical reaction \( A \to 2B \) that proceeds through the given steps, we can apply Hess's law. Here’s a step-by-step solution: ### Step 1: Understand the Reaction Steps We have three steps with their respective enthalpy changes: 1. \( A \to C \), with \(\Delta H = q\) 2. \( C \to D \), with \(\Delta H = v\) 3. \( \frac{1}{2}D \to B \), with \(\Delta H = x\) ...
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