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The enthalpies of formation of Al(2)O(3)...

The enthalpies of formation of `Al_(2)O_(3)` and `Cr_(2)O_(3)` are `-1596KJ` and `-1134KJ` respectively. `DeltaH` for the reaction
`2Al+Cr_(2)O_(3)rarr2Cr+Al_(2)O_(3)` is

A

`-2730 kJ`

B

`-462 kJ`

C

`-1365 kJ`

D

`+2730 kJ`

Text Solution

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The correct Answer is:
To find the enthalpy change (ΔH) for the reaction: \[ 2Al + Cr_2O_3 \rightarrow 2Cr + Al_2O_3 \] we will use the enthalpies of formation of the products and reactants. ### Step 1: Write down the enthalpy of formation values - The enthalpy of formation of \( Al_2O_3 \) is \( -1596 \, \text{kJ/mol} \). - The enthalpy of formation of \( Cr_2O_3 \) is \( -1134 \, \text{kJ/mol} \). - The enthalpy of formation for elements in their standard state (like \( Al \) and \( Cr \)) is \( 0 \, \text{kJ/mol} \). ### Step 2: Write the formula for ΔH The formula for calculating the enthalpy change of a reaction is: \[ \Delta H = \sum (\Delta H_f \text{ of products}) - \sum (\Delta H_f \text{ of reactants}) \] ### Step 3: Identify products and reactants In our reaction: - Products: \( 2Cr \) and \( Al_2O_3 \) - Reactants: \( 2Al \) and \( Cr_2O_3 \) ### Step 4: Substitute the enthalpy of formation values into the formula Using the values we have: \[ \Delta H = [\Delta H_f(Al_2O_3) + 2 \times \Delta H_f(Cr)] - [2 \times \Delta H_f(Al) + \Delta H_f(Cr_2O_3)] \] Since the enthalpies of formation for \( Al \) and \( Cr \) are \( 0 \): \[ \Delta H = [\Delta H_f(Al_2O_3) + 0] - [0 + \Delta H_f(Cr_2O_3)] \] Substituting the values: \[ \Delta H = [-1596 \, \text{kJ/mol}] - [-1134 \, \text{kJ/mol}] \] ### Step 5: Calculate ΔH Now, perform the calculation: \[ \Delta H = -1596 + 1134 = -462 \, \text{kJ} \] ### Final Answer Thus, the enthalpy change (ΔH) for the reaction is: \[ \Delta H = -462 \, \text{kJ} \] ---

To find the enthalpy change (ΔH) for the reaction: \[ 2Al + Cr_2O_3 \rightarrow 2Cr + Al_2O_3 \] we will use the enthalpies of formation of the products and reactants. ### Step 1: Write down the enthalpy of formation values - The enthalpy of formation of \( Al_2O_3 \) is \( -1596 \, \text{kJ/mol} \). ...
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