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Consider the following reactions: I. C...

Consider the following reactions:
I. `C(s) + 1/2 O_(2)(g) rarr CO(g)," "Delta H_(1) = x_(1)`
II. `CO(g) + 1/2 O_(2)(g) rarr CO_(2)(g), " "Delta H_(2) = x_(2)`
III. `C(s) + CO_(2)(g) rarr 2CO(g)," "Delta H_(3) = x_(3)`
Select the correct statements:

A

Heat of formation of `CO_(2)` is `(x_1 + x_2)`

B

Heat of combusion of C is `(x_1 + x_2)`

C

`Delta H_(3) = Delta H_(1) - Delta H_(2)`

D

All of the above are correct statement(s)

Text Solution

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The correct Answer is:
To solve the question regarding the given reactions and their enthalpy changes, we will analyze each reaction step by step. ### Given Reactions: 1. **Reaction I**: \( C(s) + \frac{1}{2} O_2(g) \rightarrow CO(g) \) with \( \Delta H_1 = x_1 \) 2. **Reaction II**: \( CO(g) + \frac{1}{2} O_2(g) \rightarrow CO_2(g) \) with \( \Delta H_2 = x_2 \) 3. **Reaction III**: \( C(s) + CO_2(g) \rightarrow 2CO(g) \) with \( \Delta H_3 = x_3 \) ### Step 1: Analyze the first statement **Statement 1**: The heat of formation of \( CO_2 \) is \( x_1 + x_2 \). To check this, we can combine Reaction I and Reaction II: - From Reaction I, we have \( C + \frac{1}{2} O_2 \rightarrow CO \) (enthalpy change = \( x_1 \)) - From Reaction II, we have \( CO + \frac{1}{2} O_2 \rightarrow CO_2 \) (enthalpy change = \( x_2 \)) When we add these two reactions: \[ C + \frac{1}{2} O_2 + CO + \frac{1}{2} O_2 \rightarrow CO + CO_2 \] The \( CO \) on the left cancels with \( CO \) on the right, resulting in: \[ C + O_2 \rightarrow CO_2 \] Thus, the overall enthalpy change for the formation of \( CO_2 \) is: \[ \Delta H = x_1 + x_2 \] This confirms that **Statement 1 is correct**. ### Step 2: Analyze the second statement **Statement 2**: The heat of combustion of carbon is \( x_1 + x_2 \). The heat of combustion of carbon refers to the reaction: \[ C(s) + O_2(g) \rightarrow CO_2(g) \] This reaction can also be represented as the sum of Reaction I and Reaction II: - From Reaction I: \( C + \frac{1}{2} O_2 \rightarrow CO \) (enthalpy change = \( x_1 \)) - From Reaction II: \( CO + \frac{1}{2} O_2 \rightarrow CO_2 \) (enthalpy change = \( x_2 \)) Adding these gives: \[ C + \frac{1}{2} O_2 + CO + \frac{1}{2} O_2 \rightarrow CO + CO_2 \] Again, the \( CO \) cancels out, leading to: \[ C + O_2 \rightarrow CO_2 \] Thus, the heat of combustion of carbon is indeed: \[ \Delta H = x_1 + x_2 \] This confirms that **Statement 2 is also correct**. ### Step 3: Analyze the third statement **Statement 3**: \( \Delta H_3 = \Delta H_1 - \Delta H_2 \). From Reaction III: \[ C + CO_2 \rightarrow 2CO \] We need to express this in terms of \( \Delta H_1 \) and \( \Delta H_2 \). Using Hess's law, we can manipulate the reactions: 1. Start with Reaction II in reverse: \[ CO_2 \rightarrow CO + \frac{1}{2} O_2 \quad (\Delta H = -x_2) \] 2. Then add Reaction I: \[ C + \frac{1}{2} O_2 \rightarrow CO \quad (\Delta H = x_1) \] Adding these two gives: \[ C + CO_2 \rightarrow 2CO \] Thus, the enthalpy change for this reaction is: \[ \Delta H_3 = x_1 - x_2 \] This confirms that **Statement 3 is correct**. ### Conclusion Since all three statements are correct, the final answer is: **All the above options are correct.**

To solve the question regarding the given reactions and their enthalpy changes, we will analyze each reaction step by step. ### Given Reactions: 1. **Reaction I**: \( C(s) + \frac{1}{2} O_2(g) \rightarrow CO(g) \) with \( \Delta H_1 = x_1 \) 2. **Reaction II**: \( CO(g) + \frac{1}{2} O_2(g) \rightarrow CO_2(g) \) with \( \Delta H_2 = x_2 \) 3. **Reaction III**: \( C(s) + CO_2(g) \rightarrow 2CO(g) \) with \( \Delta H_3 = x_3 \) ### Step 1: Analyze the first statement ...
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