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H(2)(g) + 1/2 O(2)(g) rightarrow H(2)O(l...

`H_(2)(g) + 1/2 O_(2)(g) rightarrow H_(2)O(l)`
`H_(2)O(f) rightarrow H_(2)O(g), Delta H = x_(4)`
Given
`E_(H-H) = x_(1)`
`E_(O=O) = x_(2)`
`E(O-H) = x_(3)`
`Delta H_(F) of H_(2)O` vapour is

A

`x_(1) + (x_2)/(2) - x_(3) + x_(4)`

B

`2x_(3) - x_(1) - (x_2)/(2) - x_(4)`

C

`x_(1) + (x_2)/(2) - 2x_(3) - x_(4)`

D

`x_(1) + (x_2)/(2) - 2x_(3) + x_(4)`

Text Solution

Verified by Experts

The correct Answer is:
C

`H_(2)(g) + 1/2 O_(2)(g) rarr H_(2)O(g)`
`Delta H_(1) = x_(1) + (x_2)/(2) - 2x_(3)`
`DeltaH_(1) = x_(1) + (x_2)/(2) - 2x_(3)`
`H_(2)O(l) rarr H_(2)O(g) Delta H_(2) = x_(4)`
Now `Delta H_(1) - Delta H_(2)`
Gives `H_(2(g)) + 1/2 O_(2_(g)) rarr H_(2)O_(l) implies Delta H_("net") i= x_(1) + (x_2)/(2) - 2x_(3) - x_(4)`.
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