Home
Class 12
CHEMISTRY
The reaction A to B , DeltaH=+24 kJ//"mo...

The reaction `A to B` , `DeltaH=+24 kJ//"mole"`. For the reaction `B to C`, `DeltaH=-18 kJ//"mole"`. The decreasing order of enthalpy of `A`, `B`, `C` follow the order

A

A,B,C

B

B,C,A

C

C,B,A

D

C,A,B

Text Solution

AI Generated Solution

The correct Answer is:
To determine the decreasing order of enthalpy for substances A, B, and C based on the given reactions and their enthalpy changes, we can follow these steps: ### Step 1: Analyze the given reactions and their enthalpy changes - The reaction from A to B has an enthalpy change (ΔH) of +24 kJ/mol. - The reaction from B to C has an enthalpy change (ΔH) of -18 kJ/mol. ### Step 2: Determine the relationship between the enthalpies of A and B Since the reaction A to B has a positive ΔH (+24 kJ/mol), this indicates that energy is absorbed when A is converted to B. Therefore, the enthalpy of B is greater than that of A: \[ H_B > H_A \] ### Step 3: Determine the relationship between the enthalpies of B and C The reaction from B to C has a negative ΔH (-18 kJ/mol), indicating that energy is released when B is converted to C. Thus, the enthalpy of C is less than that of B: \[ H_C < H_B \] ### Step 4: Combine the relationships to find the order of enthalpy From the above steps, we have: 1. \( H_B > H_A \) (B has higher enthalpy than A) 2. \( H_C < H_B \) (C has lower enthalpy than B) ### Step 5: Determine the relative positions of A, B, and C From the relationships: - We know \( H_A < H_B \) - We also know \( H_C < H_B \) Now, we need to determine the relationship between A and C. To do this, we can find the overall change in enthalpy from A to C: - The total change from A to C can be calculated as: \[ \Delta H_{A \to C} = \Delta H_{A \to B} + \Delta H_{B \to C} = +24 \text{ kJ/mol} - 18 \text{ kJ/mol} = +6 \text{ kJ/mol} \] Since this value is positive, it indicates that the enthalpy of C is greater than that of A: \[ H_C > H_A \] ### Step 6: Finalize the order of enthalpy Now we can summarize the relationships: - \( H_A < H_C < H_B \) ### Step 7: Write the decreasing order of enthalpy Thus, the decreasing order of enthalpy is: \[ H_B > H_C > H_A \] ### Final Answer The correct decreasing order of enthalpy is: **B > C > A**

To determine the decreasing order of enthalpy for substances A, B, and C based on the given reactions and their enthalpy changes, we can follow these steps: ### Step 1: Analyze the given reactions and their enthalpy changes - The reaction from A to B has an enthalpy change (ΔH) of +24 kJ/mol. - The reaction from B to C has an enthalpy change (ΔH) of -18 kJ/mol. ### Step 2: Determine the relationship between the enthalpies of A and B Since the reaction A to B has a positive ΔH (+24 kJ/mol), this indicates that energy is absorbed when A is converted to B. Therefore, the enthalpy of B is greater than that of A: ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2|50 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2 (NUMERICAL VALUE TYPE)|15 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-0 (LONG ANSWER TYPE (5 MARKS))|6 Videos
  • THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|31 Videos
  • THERMODYNAMICS & THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise Impeccable|48 Videos

Similar Questions

Explore conceptually related problems

For the reaction A + 2B to C , 5 moles of A and 8 mole of B will produce

For the reaction,, 2A + B to C + D , the order of reaction is

For the reaction A + 2B to C, 5moles of A and 8moles of B will produce :-

A reaction has DeltaH=-33kJ and DeltaS=-58J//K . This reaction would be:

The correct order of electron gain enthalpy (in kJ/mole) is

For a hypothetical reaction, A+3BrarrP DeltaH=-2x Kj//"mole" of A & M rarr 2Q+R DeltaH=+x kJ//"mole" of M These reactions are carried simultaneously in a reactor such that temperature is not changing If rate of disppearance of B is y sec^(-1) then rate of formation (in M sec^(-1)) of Q is :

VMC MODULES ENGLISH-THERMODYNAMICS-LEVEL-1
  1. A gas can expand from 100 mL to 250 mL under a constant pressure of 2 ...

    Text Solution

    |

  2. What is DeltaE for system that does 500 cal of work on surrounding an...

    Text Solution

    |

  3. The reaction A to B , DeltaH=+24 kJ//"mole". For the reaction B to C, ...

    Text Solution

    |

  4. The cooking in refrigerator is due to:

    Text Solution

    |

  5. Heat required to raise the temperature of 1 mole of a substance by 1^(...

    Text Solution

    |

  6. An ideal gas expands from 10^(-3) m^(3) to 10^(-2) m^(3) at 300 K agai...

    Text Solution

    |

  7. Match the entries of Column-I with appropriate entries of Column-II an...

    Text Solution

    |

  8. Which of the following is true for an adiabatic process:

    Text Solution

    |

  9. Consider the reaction at 300 K C(6) H(6) (l)+(15)/(2)O(2)(g)rarr6C...

    Text Solution

    |

  10. An ideal gas expands against a constant external pressure of 2.0 atmos...

    Text Solution

    |

  11. For a closed container containing 100 mole of an ideal gas fitted with...

    Text Solution

    |

  12. 10 mole of ideal gas expand isothermally and reversibly from a pressur...

    Text Solution

    |

  13. Under which of the following condition is the relation DeltaH = DeltaU...

    Text Solution

    |

  14. The work done in ergs for the reversible expansion of one mole of an i...

    Text Solution

    |

  15. The molar heat capacities at constant pressure (assumed constant with ...

    Text Solution

    |

  16. Consider the reaction at 300 K C(6) H(6) (l)+(15)/(2)O(2)(g)rarr6C...

    Text Solution

    |

  17. Give the name of the following reaction: C(2)H(5)Br+C(2)H(5)ON a to ...

    Text Solution

    |

  18. One mole of solid Zn is placed in excess of dilute H(2)SO(4) at 27^(@)...

    Text Solution

    |

  19. The enthalpy change (DeltaH) for the reaction N2(g) + 3H2 (g) to 2N...

    Text Solution

    |

  20. When 1 g of ice at 0^(@)C melts to form 1 g of water at 0^(@)C then, i...

    Text Solution

    |