Home
Class 12
CHEMISTRY
Predict which of the following reaction(...

Predict which of the following reaction(s) has a positive entropy change?
I. `Ag^(+)(aq)+Cl^(-)(aq)rarrAgCl(s)`
II. `NH_(4)Cl(s) rarrNH_(3)(g) +HCl(g)`
III. `2NH_(3)(g) rarr N_(2)(g)+3H_(2)(g)`

A

I and II

B

III

C

II and III

D

II

Text Solution

Verified by Experts

The correct Answer is:
C

In I part, entropy is decreasing as solid is formed
In II and III, entropy is increasing as gaseous moles re increasing
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2|50 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2 (NUMERICAL VALUE TYPE)|15 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-0 (LONG ANSWER TYPE (5 MARKS))|6 Videos
  • THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|31 Videos
  • THERMODYNAMICS & THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise Impeccable|48 Videos

Similar Questions

Explore conceptually related problems

Predict which of the following reaction (s) has a positive entropy change? I . Ag^(+)(aq)+Cl^(-)(aq)rarrAgCl(s) II . NH_(4)Cl(s)rarrNH_(3)(g)+HCl(g) III . 2NH_(3)(g)rarrN_(2)+3H_(2)(g)

Predict which of the following reaction(s) has a negative entropy change? I. CH_(4)(g) +2O_(2)(g)rarrCO_(2)(g)+2H_(2)O(l) II. NH_(3)(g)+HCl(g)rarrNH_(4)Cl(s) III. 2KClO_(4)(s) rarr2KClO_(3)(s)+O_(2)(g)

Determine which of the following reactions at constant pressure represent systems that do work on the surrounding environment I. Ag^(+) (aq) + Cl^(-) (aq) rarr AgCl(s) II. NH_(4)Cl(s) rarr NH_(3) (g) + HCl (g) III. 2NH_(3)(g) rarr N_(2)(g) + 3H_(2)(g)

Determine which of the following reactions taking place at constant pressure represents system that do work on the surrounding environment (I) Ag^(+)(aq)+Cl^(-)(aq)rarrAgCl(s)" (II) NH_(4)Cl(s)rarrNH_(3)(g)+HCl(g) " (III) 2NH_(3)(g)rarrN_(2)(g)+3H_(2)(g)

Predict which of the following reactions have positive entropy changes. (a) NH_(3(g))+HCl_((g))rarrNH_(4)Cl_((s)) (b) Cu_((aq))^(+2)+S_((aq))^(-2)rarrCuS_((s)) (c ) NH_(2)COONH_(4(s))rarr2NH_(3(g))+CO_(2(g)) (d) Condensation of water

Why are the following reactions not redox reactions ? AgNO_(3)(aq)+HCl(aq)toHNO_(3)(aq)+Ag(Cl)(s)

For which of the following reactions, the degree of dissociation cannot be calculated from the vapour density data. I. 2HI_((g))hArrH_(2(g))+I_(2(g)) II. 2NH_(3(g))hArrN_(2(g))+3H_(2(g)) III. 2NO_((g))hArrN_(2(g))+O_(2(g)) IV. PCl_(5(g))hArr PCl_(3(g))+Cl_(2(g))

Write balanced net ionic equations for the following reactions in basic solution: (a) H_(2)O_(2)(aq)+ClO_(4)^(Ө)(aq) rarr ClO_(2)^(Ө)(aq)+O_(2)(g) (b) ( c) Cu(OH)_(2)(s) + N_(2)H_(4)(aq) rarr Cu(s)+N_(2)(g) (d) MnO_(4)^(Ө) + IO_(3)^(Ө)(aq)rarr MnO_(2)(s) + IO_(4)^(Ө)(aq)

Determine which of the following reactions at constant pressure represents surroundings that do work on the system: I. 4NH_(3)(g)+7O_(2)(g)rarr4NO_(2)(g)+6H_(2)O(g) II. CO(g)+2H_(2)(g)rarrCH_(3)OH(l) III. C(s,"graphite")+H_(2)O(g)rarrCO(g)+H_(2)(g) IV. H_(2)OrarrH_(2)O(l)

Which of the following reaction is correct for a given electrochemical cell at 25^(@)C ? (PtBr_(2)(g)Br^()(g)||Cl^(-)(aq) Cl_(2) (g)pt

VMC MODULES ENGLISH-THERMODYNAMICS-LEVEL-1
  1. One mole of an ideal gas is expanded from a volume of 3L to 5L under a...

    Text Solution

    |

  2. For the reaction 2HgO(s) rarr 2Hg(l) + O(2)(g)

    Text Solution

    |

  3. Predict which of the following reaction(s) has a positive entropy chan...

    Text Solution

    |

  4. Which of the following is/are state function?

    Text Solution

    |

  5. The enthalpy of vaporisation of a liquid is 30 kJ mol^(-1) and entropy...

    Text Solution

    |

  6. When the gas is ideal and process is isothermal, then

    Text Solution

    |

  7. A system absorbs 300cal of heat , its volume doubles and temperature r...

    Text Solution

    |

  8. Temperature of one mole of a gas is increased by 1^(@) C at constant p...

    Text Solution

    |

  9. P-V plot for two gases (assuming ideal) during adiabatic processes are...

    Text Solution

    |

  10. Calculate the final temperature of a monoatomic ideal gas that is comp...

    Text Solution

    |

  11. The adsorption of vapours on a clean surface is a spontaneous process ...

    Text Solution

    |

  12. Column-I and Column-II contains four entries each. Entries of Column-I...

    Text Solution

    |

  13. Match Column-I with Column-II and select the correct answer using the ...

    Text Solution

    |

  14. A process is taking place at constant temperature and pressure. Then

    Text Solution

    |

  15. In view of the signs of DeltarG^@ for the following reactions PbO2 +...

    Text Solution

    |

  16. A plot of ln k against (1)/(T) (abscissa) is expected to be a straight...

    Text Solution

    |

  17. The correct relationship between free energy change in a reaction and ...

    Text Solution

    |

  18. For the reaction at 298 K A(g) + B(g) hArr C(g) + D(g) If DeltaH^(...

    Text Solution

    |

  19. एंटोपि का मात्रक है ---

    Text Solution

    |

  20. For a system in equilibrium, DeltaG=0, under conditions of constant

    Text Solution

    |