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The standard reaction Gibbs energy for...

The standard reaction Gibbs energy for a temperature T is given by
`Delta_(r)G^(@)= A-Bt`
Where A and B are non-zero constants.
Which of the following is TRUE about this reaction ?

A

Exothermic if `B lt 0`

B

Exothermic if `A gt 0` and `B lt 0`

C

Endothermic if `A lt 0` and `B gt 0`

D

Endothermic if `A gt 0`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given equation for the standard reaction Gibbs energy: \[ \Delta_r G^\circ = A - BT \] where \( A \) and \( B \) are non-zero constants, and \( T \) is the temperature. ### Step-by-step Solution: 1. **Understanding the Gibbs Free Energy Equation**: The Gibbs free energy change for a reaction at standard conditions is given by: \[ \Delta G^\circ = \Delta H^\circ - T \Delta S^\circ \] where \( \Delta H^\circ \) is the change in enthalpy and \( \Delta S^\circ \) is the change in entropy. 2. **Setting the Given Equation**: We compare the provided equation \( \Delta_r G^\circ = A - BT \) with the standard Gibbs free energy equation. This gives us: \[ A = \Delta H^\circ \quad \text{and} \quad -B = -\Delta S^\circ \] Therefore, we can deduce: \[ \Delta S^\circ = B \] 3. **Determining Spontaneity**: A process is spontaneous when \( \Delta G^\circ < 0 \). Thus, we set up the inequality: \[ A - BT < 0 \] Rearranging this gives: \[ A < BT \] 4. **Analyzing the Conditions**: - If \( A < BT \), then as temperature \( T \) increases, the term \( BT \) increases, which means that for a given \( B \), there will be a temperature above which the reaction becomes spontaneous. - If \( A \) is a constant and \( B \) is positive, then there exists a temperature \( T \) such that the reaction can switch from non-spontaneous to spontaneous. 5. **Considering the Sign of \( A \)**: - If \( A > 0 \), then \( \Delta H^\circ \) is positive, indicating an endothermic reaction. - If \( A < 0 \), then \( \Delta H^\circ \) is negative, indicating an exothermic reaction. 6. **Conclusion**: Since \( A \) is a constant and we are looking for conditions under which the reaction can be spontaneous, we conclude that if \( A > 0 \), the reaction is endothermic. Thus, the correct statement about the reaction is that it is endothermic if \( A > 0 \). ### Final Answer: The correct statement about this reaction is that it is **endothermic if \( A > 0 \)**.

To solve the problem, we need to analyze the given equation for the standard reaction Gibbs energy: \[ \Delta_r G^\circ = A - BT \] where \( A \) and \( B \) are non-zero constants, and \( T \) is the temperature. ...
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