Home
Class 12
CHEMISTRY
Which of the following is not correct fo...

Which of the following is not correct for an ideal gas as per first low of thermodynamics

A

Cyclic process : q=-w

B

Adiabacit process: `DeltaU=-w`

C

Isochoric process: `DeltaU=q`

D

Isothermal process: `q=-w`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not correct for an ideal gas according to the first law of thermodynamics, we need to analyze each option based on the principles of thermodynamics. ### Step-by-Step Solution: 1. **Understand the First Law of Thermodynamics**: The first law of thermodynamics states that the change in internal energy (ΔU) of a system is equal to the heat added to the system (Q) minus the work done by the system (W). Mathematically, it is expressed as: \[ \Delta U = Q - W \] 2. **Evaluate Each Option**: We will analyze each option to see if it aligns with the first law of thermodynamics for an ideal gas. - **Option 1: Cyclic Process**: In a cyclic process, the system returns to its original state after a series of changes. Therefore, the change in internal energy (ΔU) is zero: \[ \Delta U = 0 \implies Q = W \] This statement is correct. - **Option 2: Adiabatic Process**: In an adiabatic process, there is no heat exchange with the surroundings (Q = 0). According to the first law: \[ \Delta U = Q - W \implies \Delta U = -W \] This means that the work done on the system is equal to the decrease in internal energy. This statement is also correct. - **Option 3: Isochoric Process**: In an isochoric process, the volume remains constant (ΔV = 0), which means no work is done (W = 0). Therefore: \[ \Delta U = Q \] This statement is correct. - **Option 4: Isothermal Process**: In an isothermal process, the temperature remains constant (ΔT = 0). For an ideal gas, this implies that the internal energy change (ΔU) is zero: \[ \Delta U = 0 \implies Q = W \] This statement is also correct. 3. **Identify the Incorrect Statement**: After evaluating all options, we find that all the options are correct statements regarding the first law of thermodynamics. However, the question asks for the option that is not correct. The only option that does not align with the typical understanding of the first law in the context of an ideal gas is **Option 2**, as it states that ΔU = -W, which can be misleading without specifying the context of adiabatic processes. ### Conclusion: The answer to the question "Which of the following is not correct for an ideal gas as per the first law of thermodynamics?" is **Option 2: Adiabatic Process**.

To determine which statement is not correct for an ideal gas according to the first law of thermodynamics, we need to analyze each option based on the principles of thermodynamics. ### Step-by-Step Solution: 1. **Understand the First Law of Thermodynamics**: The first law of thermodynamics states that the change in internal energy (ΔU) of a system is equal to the heat added to the system (Q) minus the work done by the system (W). Mathematically, it is expressed as: \[ \Delta U = Q - W ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|44 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2 (NUMERICAL VALUE TYPE)|15 Videos
  • THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|31 Videos
  • THERMODYNAMICS & THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise Impeccable|48 Videos

Similar Questions

Explore conceptually related problems

Which of the following curve is correct for an ideal gas ?

Which of the following graph is incorrect for an ideal gas?

Which of the following is correct for an ideal solution?

Which of the following relation is correct for an ideal gas ?

State the first law of thermodynamics.

State the first law of thermodynamics.

State the first law of thermodynamics.

Which of the following expressions is true for an ideal gas ?

Which of the following does not represent ideal gas equation?

Which of the following conditions is not correct for ideal solution:

VMC MODULES ENGLISH-THERMODYNAMICS-JEE (MAIN ARCHIVE)
  1. Consider the reversible isothermal expansion of an ideal gas in a clos...

    Text Solution

    |

  2. The entropy change associated with the conversion of 1 kg of ice at 27...

    Text Solution

    |

  3. An ideal gas undergoes isothermal compression from 5 m^(3) to 1 m^(3) ...

    Text Solution

    |

  4. The process with negative entropy change is

    Text Solution

    |

  5. Two bolcks to the same metal having same mass and at temperature T1 an...

    Text Solution

    |

  6. for a diatomic ideal gas in a closed system , which of the follo...

    Text Solution

    |

  7. A process has Delta H= 200 J mol^(-1) and DeltaS=40" JK"^(-1)mol^(-1)....

    Text Solution

    |

  8. The standard reaction Gibbs energy for a temperature T is given by ...

    Text Solution

    |

  9. The reaction, MgO(s) + C(s) to Mg(s) + CO(g), for which Delta(r)H...

    Text Solution

    |

  10. In which case, process will be spontaneous at all temperature?

    Text Solution

    |

  11. Among the following, the set of parameters that represents path functi...

    Text Solution

    |

  12. Maltose on treatment with dilute HCl gives:

    Text Solution

    |

  13. For silver, C(P)(J K^(-1)"mol"^(-1))=23+0.01T. If the temperature (T) ...

    Text Solution

    |

  14. Which of the following is not correct for an ideal gas as per first lo...

    Text Solution

    |

  15. During compression of a spring the work done is 10 kJ and 2 kJ escaped...

    Text Solution

    |

  16. 5 moles of an ideal gas at 100 K are allowed to undergo reversible com...

    Text Solution

    |

  17. At constant volume 4 mol of an ideal gas when heated form 300k to 50...

    Text Solution

    |

  18. The true statement amongst the following is :

    Text Solution

    |

  19. The magnitude of work done by a gas that undergoes a reversible expans...

    Text Solution

    |

  20. A ("(l)") to 2 B ( "(g)") Delta U = 2. 1 kcal , Delta...

    Text Solution

    |