Home
Class 12
CHEMISTRY
3 moles of A and 4 moles of B are mixed ...

3 moles of A and 4 moles of B are mixed together and allowed to come into equilibrium according to the following reaction.
`3A(g) + 4B(g) rarr 2C(g) + 3D(g)`
When equilibrium is reached, there is 1 mole of C. The equilibrium constant of the reaction is

A

`(1/4)^(4)`

B

`(1/3)^(3)`

C

`(1/2)^(4)`

D

1

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant \( K_c \) for the reaction \( 3A(g) + 4B(g) \rightleftharpoons 2C(g) + 3D(g) \), we will follow these steps: ### Step 1: Write the balanced chemical equation The balanced reaction is: \[ 3A(g) + 4B(g) \rightleftharpoons 2C(g) + 3D(g) \] ### Step 2: Set up the initial moles of reactants and products Initially, we have: - Moles of \( A = 3 \) - Moles of \( B = 4 \) - Moles of \( C = 0 \) - Moles of \( D = 0 \) ### Step 3: Define the change in moles at equilibrium Let \( x \) be the change in moles of \( C \) formed at equilibrium. According to the stoichiometry of the reaction: - For every 2 moles of \( C \) formed, 3 moles of \( A \) and 4 moles of \( B \) are consumed. Thus, at equilibrium: - Moles of \( A = 3 - \frac{3}{2}x \) - Moles of \( B = 4 - 2x \) - Moles of \( C = 2x \) - Moles of \( D = \frac{3}{2}x \) ### Step 4: Use the information given We are given that at equilibrium, there is 1 mole of \( C \): \[ 2x = 1 \] Thus, solving for \( x \): \[ x = \frac{1}{2} \] ### Step 5: Calculate the equilibrium moles Substituting \( x = \frac{1}{2} \) into the expressions for moles at equilibrium: - Moles of \( A = 3 - \frac{3}{2} \times \frac{1}{2} = 3 - \frac{3}{4} = \frac{9}{4} \) - Moles of \( B = 4 - 2 \times \frac{1}{2} = 4 - 1 = 3 \) - Moles of \( C = 2 \times \frac{1}{2} = 1 \) - Moles of \( D = \frac{3}{2} \times \frac{1}{2} = \frac{3}{4} \) ### Step 6: Write the expression for the equilibrium constant \( K_c \) The equilibrium constant \( K_c \) is given by: \[ K_c = \frac{[C]^2[D]^3}{[A]^3[B]^4} \] ### Step 7: Substitute the equilibrium concentrations Assuming the volume of the reaction vessel is 1 liter (for simplicity): - \([A] = \frac{9}{4} \, \text{mol/L}\) - \([B] = 3 \, \text{mol/L}\) - \([C] = 1 \, \text{mol/L}\) - \([D] = \frac{3}{4} \, \text{mol/L}\) Now substituting these values into the expression for \( K_c \): \[ K_c = \frac{(1)^2 \left(\frac{3}{4}\right)^3}{\left(\frac{9}{4}\right)^3 (3)^4} \] ### Step 8: Simplify the expression Calculating the numerator: \[ (1)^2 \left(\frac{3}{4}\right)^3 = \frac{27}{64} \] Calculating the denominator: \[ \left(\frac{9}{4}\right)^3 = \frac{729}{64} \quad \text{and} \quad (3)^4 = 81 \] Thus, \[ K_c = \frac{\frac{27}{64}}{\frac{729}{64} \times 81} = \frac{27}{729 \times 81} \] ### Step 9: Final calculation Calculating \( 729 \times 81 = 59049 \): \[ K_c = \frac{27}{59049} \] ### Step 10: Simplifying further Recognizing that \( 59049 = 3^{10} \) and \( 27 = 3^3 \): \[ K_c = \frac{3^3}{3^{10}} = \frac{1}{3^7} = \frac{1}{2187} \] ### Final Answer Thus, the equilibrium constant \( K_c \) is: \[ K_c = \frac{1}{2187} \]

To find the equilibrium constant \( K_c \) for the reaction \( 3A(g) + 4B(g) \rightleftharpoons 2C(g) + 3D(g) \), we will follow these steps: ### Step 1: Write the balanced chemical equation The balanced reaction is: \[ 3A(g) + 4B(g) \rightleftharpoons 2C(g) + 3D(g) \] ### Step 2: Set up the initial moles of reactants and products Initially, we have: ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise Level 2|65 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|24 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise Level 0 LA|6 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos
  • CHEMICAL KINETICS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|52 Videos

Similar Questions

Explore conceptually related problems

At a certain temperture in a 5L vessel 2 moles of carbon monoxide and 3 moles of chlorine were allowed to reach equilibrium according to the reaction CO+CI_(2) rarr COCI_(2) at equlibrium if one mole of CO is present then equilibrium constant (k_(c )) for the reaction is :

At a certain temperature 2 moles of carbonmonoxide and 3 moles of chlorine were allowed to reach equilibrium according to the reaction CO+Cl_(2)hArrCOCl_(2) in a 5 lit vessel. At equilibrium if one mole of CO is present then equilibrium constant for the reaction is :

When 3.00 mole of A and 1.00 mole of B are mixed in a 1,00 litre vessel , the following reaction takes place A(g) +B(g) hArr 2C(g) the equilibrium mixture contains 0.5 mole of C. What is the value of equilibrium constant for the reaction ?

4 moles of A are mixed with 4 moles of B, when 2 moles of C are formed at equilibrium according to the reaction A+B hArr C+D . The value of equilibrium constant is

10 moles of A_(2), 15 moles of B_(2) and 5 moles of AB are placed in a 2 litre vessel and allowed the come to equilibrium. The final concentration of AB is 10.5 M, A_(2)(g)+B_(2)(g)hArr 2AB(g) Determine the value of equilibrium constant (K_(C)) for the reaction.

A+B rarr C+D Initially moles of A and B are equal. At equilibrium, moles of C are three times of A. The equilibrium constant of the reaction will be

Two moles of each reactant A and B are taken in a reaction flask. They react in the following manner, A(g)+B(g)hArr C(g)+D(g) At equilibrium, it was found that the concentration of C is triple to that of B the equilibrium constant for the reaction is

In the following reaction, 3A (g)+B(g) hArr 2C(g) +D(g) , Initial moles of B is double at A . At equilibrium, moles of A and C are equal. Hence % dissociation is :

1.1 mole of A and 2.2 moles of B reach an cquilibrium in I lit container according to the reaction. A + 2B hArr 2C + D. If at equilibrium 0.1 mole of D is present, the equilibrium constant is:

1.1 moles of A are mixed with 2.2 moles of B and the mixture is kept in a one litre flask till the equilibrium A+ 2B hArr 2C + D is reached. At equilibrium, 0.2 moles of C are formed. The equilibrium constant of the reaction is

VMC MODULES ENGLISH-CHEMICAL EQUILIBRIUM-Level 1
  1. Consider the following two gaseous equilibria involving SO2 and the co...

    Text Solution

    |

  2. NH(4)HS(s) hArr NH(3)(g)+H(2)S(g) In the above reaction, if the pres...

    Text Solution

    |

  3. 3 moles of A and 4 moles of B are mixed together and allowed to come i...

    Text Solution

    |

  4. Which of the following is a wrong statement about equilibrium state ?

    Text Solution

    |

  5. A+B rarr C+D Initially moles of A and B are equal. At equilibrium, mol...

    Text Solution

    |

  6. Which of the following is not a physical equilibrium ?

    Text Solution

    |

  7. 2HI(g) rarr H(2)(g) + I(2)(g) The equilibrium constant of the above re...

    Text Solution

    |

  8. For a reaction at equilibrium which of the following is correct ?

    Text Solution

    |

  9. Consider the reaction :- 2CO(g)+2H(2)O((g))hArr2CO(2(g))+2H(2(g))eq....

    Text Solution

    |

  10. For the following reaction in gaseous phase CO(g)+1/2O(2) rarr CO(2) K...

    Text Solution

    |

  11. Three moles of PCl(5), three moles of PCl(3) and two moles of Cl(2) ar...

    Text Solution

    |

  12. One mole of H(2) and 2 moles of I(2) are taken initially in a two lit...

    Text Solution

    |

  13. On doubling P and V at constant temperature, the equilibrium constant ...

    Text Solution

    |

  14. For the reaction, 2HI(g) rarr H(2)(g) + I(2) (g) - Q KJ , the equilibr...

    Text Solution

    |

  15. 1.6 mol of PCl(5)(g) is placed in 4 dm^(-3) closed vessel. When the te...

    Text Solution

    |

  16. Ammonium carbamate decomposes as : NH(2)COONH(4) (s) rarr 2NH(3)(g) ...

    Text Solution

    |

  17. 4 moles each of SO(2) "and" O(2) gases are allowed to react to form SO...

    Text Solution

    |

  18. In chemical equilibrium, the value of Delta n (number of molecules), i...

    Text Solution

    |

  19. K(p)//K(c) for the reaction CO(g)+1/2 O(2)(g) hArr CO(2)(g) is

    Text Solution

    |

  20. The equilibrium constant (K(c)) of the reaction A(2)(g) + B(2)(g) rarr...

    Text Solution

    |