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HX is a weak acid (K(a) = 10^(-5)). If f...

`HX` is a weak acid `(K_(a) = 10^(-5))`. If forms a salt `NaX(0.1M)` on reacting with caustic soda. The degree of hydrlysis of `NaX` in % is

A

0.01

B

0.0001

C

0.1

D

0.5

Text Solution

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The correct Answer is:
To find the degree of hydrolysis of the salt `NaX` formed from the weak acid `HX` (with \( K_a = 10^{-5} \)), we can follow these steps: ### Step 1: Determine the Hydrolysis Constant \( K_h \) For a salt formed from a weak acid and a strong base, the hydrolysis constant \( K_h \) can be calculated using the formula: \[ K_h = \frac{K_w}{K_a} \] Where: - \( K_w = 10^{-14} \) (the ion product of water) - \( K_a = 10^{-5} \) (the dissociation constant of the weak acid) Substituting the values: \[ K_h = \frac{10^{-14}}{10^{-5}} = 10^{-9} \] ### Step 2: Calculate the Degree of Hydrolysis \( h \) The degree of hydrolysis \( h \) can be calculated using the formula: \[ h = \sqrt{\frac{K_h}{C}} \] Where: - \( K_h = 10^{-9} \) - \( C = 0.1 \, \text{M} \) (the concentration of the salt \( NaX \)) Substituting the values: \[ h = \sqrt{\frac{10^{-9}}{0.1}} = \sqrt{10^{-8}} = 10^{-4} \] ### Step 3: Convert Degree of Hydrolysis to Percentage To express \( h \) as a percentage, we multiply by 100: \[ \text{Degree of Hydrolysis in \%} = h \times 100 = 10^{-4} \times 100 = 10^{-2} = 0.01\% \] ### Final Answer The degree of hydrolysis of \( NaX \) in percentage is **0.01%**. ---

To find the degree of hydrolysis of the salt `NaX` formed from the weak acid `HX` (with \( K_a = 10^{-5} \)), we can follow these steps: ### Step 1: Determine the Hydrolysis Constant \( K_h \) For a salt formed from a weak acid and a strong base, the hydrolysis constant \( K_h \) can be calculated using the formula: \[ K_h = \frac{K_w}{K_a} ...
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