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The solubility product of a salt having ...

The solubility product of a salt having general formula `MX_(2)` in water is `4xx10^(-12)`. The concentration of `M^(2+) ions` in the aqueous solution of the salt is:

A

`2xx10^(-6)`M

B

`1xx10^(-4)`M

C

`1.6xx10^(-4)`M

D

`4.0xx10^(-6)`M

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The correct Answer is:
To solve the problem, we need to determine the concentration of \( M^{2+} \) ions in a saturated solution of the salt \( MX_2 \) given its solubility product \( K_{sp} = 4 \times 10^{-12} \). ### Step-by-Step Solution: 1. **Write the Dissociation Equation**: The salt \( MX_2 \) dissociates in water as follows: \[ MX_2 \rightleftharpoons M^{2+} + 2X^{-} \] 2. **Define Solubility**: Let the solubility of \( MX_2 \) be \( s \) mol/L. Then, at equilibrium: - The concentration of \( M^{2+} \) ions will be \( s \). - The concentration of \( X^{-} \) ions will be \( 2s \). 3. **Write the Expression for \( K_{sp} \)**: The solubility product \( K_{sp} \) is given by the expression: \[ K_{sp} = [M^{2+}][X^{-}]^2 \] Substituting the concentrations from the dissociation: \[ K_{sp} = (s)(2s)^2 = s \cdot 4s^2 = 4s^3 \] 4. **Substitute the Given \( K_{sp} \)**: We know that \( K_{sp} = 4 \times 10^{-12} \). Therefore, we can set up the equation: \[ 4s^3 = 4 \times 10^{-12} \] 5. **Solve for \( s^3 \)**: Dividing both sides by 4: \[ s^3 = 10^{-12} \] 6. **Calculate \( s \)**: To find \( s \), take the cube root: \[ s = (10^{-12})^{1/3} = 10^{-4} \] 7. **Determine the Concentration of \( M^{2+} \)**: Since \( s \) represents the concentration of \( M^{2+} \) ions: \[ [M^{2+}] = s = 10^{-4} \text{ mol/L} \] ### Final Answer: The concentration of \( M^{2+} \) ions in the aqueous solution of the salt is: \[ \boxed{1 \times 10^{-4} \text{ mol/L}} \]

To solve the problem, we need to determine the concentration of \( M^{2+} \) ions in a saturated solution of the salt \( MX_2 \) given its solubility product \( K_{sp} = 4 \times 10^{-12} \). ### Step-by-Step Solution: 1. **Write the Dissociation Equation**: The salt \( MX_2 \) dissociates in water as follows: \[ MX_2 \rightleftharpoons M^{2+} + 2X^{-} ...
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