Home
Class 12
CHEMISTRY
The vapour pressure of an aqueous soluti...

The vapour pressure of an aqueous solution of glucose is `750 mm` of `Hg` at `373 K`. Calculate molality and mole fraction of solute.

A

0.64

B

0.741

C

0.68

D

0.94

Text Solution

Verified by Experts

`(P^(@)-P_(s))/(P^(s))=(w_(1)xxm_(2))/(m_(1)xxw_(2))` (Assuming the solution to be dilute and remembering that at 373K the equilibrium vapour pressure of water is 760 mm of Hg).
`implies(P^(@)-P_(s))/(P_(s))=((w_(1)xx1000))/((m_(1)xxw_(2)))xx(m_(2))/1000xx(m_(2))/1000=Mxx(m_(2))/(1000implies(760-750)/750)=Mxx18/1000`
`M=(10xx1000)/(750xx18)=0.741` mol/kg of solvent.
Promotional Banner

Topper's Solved these Questions

  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|57 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise LEVEL 1|75 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE-J|10 Videos
  • THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|31 Videos

Similar Questions

Explore conceptually related problems

The vapour pressure of a dilute aqueous solution of glucose is 700 mm of Hg at 373 K . Calculate the (a) molality and (b) mole fraction of the solute.

If the vapor pressure of a dilute aqueous solution of glucose is 750 mm of Hg at 373 K , then molality of solute is

The vapour pressure of a dilute aqueous solution of glucose is 750 mmHg at 373 K. The mole fraction of the solute is

The vapour pressure of a dilute aqueous solution of glucosse (C_(6)H_(12)O_(6)) is 750 mm Hg at 273 K . Calculate (a) molality and (b) mole fraction of the solute.

Calculate the vapour pressure of an aqueous solution of 1.0 molal glucose solution at 100^(@)C .

Benzene and toluene form nearly ideal solution. If at 300K P_("bentezne")=103.01 mm. (i) Calculate the vapour pressure of a solution containing 0.6 mole fraction of toluene. (ii) Calculate the mole fraction of toluene in the vapour form for this composition of liquid.

Assertion:The vapour pressure of an aqueous solution of sucrose is less than 1.013 bar at 373.15 K Reason : Vapour pressure of water is 1.013 bar at 373.15 K.

The vapour pressure of a pure liquid A at 300 K is 150 torr. The vapour pressure of this liquid in a solution with a liquid Bis 105 torr. Calculate the mole fraction of A in the solution if the mixture obey's Raoult's law.

The vapour pressure of pure benzene at 25^(@)C is 639.7 mm Hg and vapour pressure of a solution of solute in benzene at the same temperature is 631.9 mm Hg. Calculate the molality of the solution.

The vapour pressure of methyl alcohol at 298 K is 0.158 bar. The vapour pressure of this liquid in solution with liquid B is 0.095 bar. Calculate the mole fraction of methyl alcohol in the solution if the mixture obeys Raoult's law.

VMC MODULES ENGLISH-THEORY OF SOLUTIONS-LEVEL 2
  1. M(n)= Normal molecular mass of solute M(0)= Observed molecule mass o...

    Text Solution

    |

  2. At 17^(@)C, the osmotic pressure of sugar solution is 580 torr. The so...

    Text Solution

    |

  3. The vapour pressure of an aqueous solution of glucose is 750 mm of Hg ...

    Text Solution

    |

  4. The boiling point of an aqueous solution of a non-volatile solute is 1...

    Text Solution

    |

  5. The relative lowering of vapour pressure of an aqueous solution of a n...

    Text Solution

    |

  6. Calculate the entropy change for vapourisation of water if latent heat...

    Text Solution

    |

  7. We have 200 mL of 6% urea solution at 27^(@)C. Osmotic pressure due to...

    Text Solution

    |

  8. Two equimolar solutions have osmotic pressures in the ratio of 2 : 1 a...

    Text Solution

    |

  9. Human blood gives rise to an osmotic pressure of approximately 7.65 at...

    Text Solution

    |

  10. Osmotic pressure of insulin solution at 298 K is found to be 0.0072atm...

    Text Solution

    |

  11. Out of the compounds below, the vapour pressure of (B) at a particular...

    Text Solution

    |

  12. How much urea must be dissolved in 10^(-2)m^(3) water to yield a press...

    Text Solution

    |

  13. Acetic acid exists in benzene solution in the dimeric form. In an actu...

    Text Solution

    |

  14. Calculate the mass of a non-volatile solute (molar mass 40 g mol^(-1))...

    Text Solution

    |

  15. 1000gm of sucrose solution in water is cooled to -0.5^(@)C. How much ...

    Text Solution

    |

  16. The depression in freezing point of 0.01 m aqueous CH(3)CooH solution ...

    Text Solution

    |

  17. When 20 g of naphthoic acid (C(11)H(8)O(2)) is dissolved in 50 g of be...

    Text Solution

    |

  18. 75.2 g of phenol is dissolved in a solvent of Kf=14. If the depression...

    Text Solution

    |

  19. A storage battery contains a solution of H(2)SO(4) 38% by weight. At t...

    Text Solution

    |

  20. Calculate the apparent degree of ionisation of an electrolyte MX(2) i...

    Text Solution

    |