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Assertion :- Equivalent weight of NH(3) ...

Assertion :- Equivalent weight of `NH_(3)` in the reaction `N_(2) rarrNH_(3)` is `17//3` while that of `N_(2)` is `28//6`.
Reason :- `"Equivalent weight" =("Molecular weight")/("number of "e^(-)" lost or gained/mole")`

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To solve the question, we need to analyze the assertion and reason regarding the equivalent weights of NH₃ and N₂ in the reaction N₂ → NH₃. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction we are considering is: \[ N_2 \rightarrow NH_3 \] 2. **Determine the Oxidation States**: - In \(N_2\), nitrogen has an oxidation state of 0. - In \(NH_3\), nitrogen has an oxidation state of -3. 3. **Calculate the Change in Electrons**: - The change in oxidation state from 0 to -3 indicates that nitrogen is gaining electrons. - Each nitrogen atom in \(N_2\) gains 3 electrons. Since there are 2 nitrogen atoms in \(N_2\), the total number of electrons gained is: \[ 2 \times 3 = 6 \text{ electrons} \] 4. **Calculate the Equivalent Weight of NH₃**: - The molecular weight (gram molecular mass, GMM) of \(NH_3\) is 17 g/mol. - The number of electrons gained per mole (N factor) for \(NH_3\) is 3. - Therefore, the equivalent weight of \(NH_3\) is calculated as: \[ \text{Equivalent weight of } NH_3 = \frac{\text{Molecular weight}}{\text{N factor}} = \frac{17}{3} \text{ g/equiv} \] 5. **Calculate the Equivalent Weight of N₂**: - The molecular weight of \(N_2\) is 28 g/mol. - The N factor for \(N_2\) is the total number of electrons gained by both nitrogen atoms, which is 6 (as calculated earlier). - Thus, the equivalent weight of \(N_2\) is: \[ \text{Equivalent weight of } N_2 = \frac{\text{Molecular weight}}{\text{N factor}} = \frac{28}{6} \text{ g/equiv} \] 6. **Conclusion**: - The assertion states that the equivalent weight of \(NH_3\) is \(17/3\) and that of \(N_2\) is \(28/6\). Both of these calculations are correct. - The reason provided states that "Equivalent weight = (Molecular weight) / (number of electrons lost or gained per mole)", which is indeed the formula used to derive the equivalent weights. ### Final Answer: - Both the assertion and reason are correct, and the reason is the correct explanation of the assertion.

To solve the question, we need to analyze the assertion and reason regarding the equivalent weights of NH₃ and N₂ in the reaction N₂ → NH₃. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction we are considering is: \[ N_2 \rightarrow NH_3 ...
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