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For a reaction (1)/(2)A rarr 2B, rate of...

For a reaction `(1)/(2)A rarr 2B`, rate of disappearance of `'A'` is related to the rate of apperance of `'B'` by the expression:

A

`-(d[A])/(dt) =(1)/(2) (d[B])/(dt)`

B

`-(d[A])/(dt) =(1)/(4) (d[B])/(dt)`

C

`-(d[A])/(dt) =(d[B])/(dt)`

D

`-(d[A])/(dt) =4(d[B])/(dt)`

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To solve the problem, we need to relate the rate of disappearance of reactant A to the rate of appearance of product B for the reaction: \[ \frac{1}{2} A \rightarrow 2B \] ### Step-by-Step Solution: 1. **Write the Rate Expressions**: For the reaction, we can express the rate of disappearance of A and the rate of appearance of B using their stoichiometric coefficients. The rate of disappearance of A can be expressed as: \[ -\frac{1}{\text{stoichiometric coefficient of A}} \frac{d[A]}{dt} = -\frac{1}{\frac{1}{2}} \frac{d[A]}{dt} = -2 \frac{d[A]}{dt} \] The rate of appearance of B can be expressed as: \[ \frac{1}{\text{stoichiometric coefficient of B}} \frac{d[B]}{dt} = \frac{1}{2} \frac{d[B]}{dt} \] 2. **Set Up the Relationship**: According to the stoichiometry of the reaction, we can relate these two rates: \[ -2 \frac{d[A]}{dt} = \frac{1}{2} \frac{d[B]}{dt} \] 3. **Rearranging the Equation**: To find the relationship between the rates, we can rearrange the equation: \[ -2 \frac{d[A]}{dt} = \frac{1}{2} \frac{d[B]}{dt} \] Multiply both sides by 2: \[ -4 \frac{d[A]}{dt} = \frac{d[B]}{dt} \] 4. **Final Expression**: We can express the rate of disappearance of A in terms of the rate of appearance of B: \[ -\frac{d[A]}{dt} = \frac{1}{4} \frac{d[B]}{dt} \] ### Conclusion: Thus, the relationship between the rate of disappearance of A and the rate of appearance of B is given by: \[ -\frac{d[A]}{dt} = \frac{1}{4} \frac{d[B]}{dt} \]

To solve the problem, we need to relate the rate of disappearance of reactant A to the rate of appearance of product B for the reaction: \[ \frac{1}{2} A \rightarrow 2B \] ### Step-by-Step Solution: ...
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