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The following statement(s) is (are) corr...

The following statement(s) is (are) correct:

A

A plot of log `k_(p)` versus 1/T is linear

B

A plot of log [X] versus time is linear for a first-order reaction, `X rarr P`

C

A plot of P versus 1/T is linear at constant volume

D

A plot of P versus 1/V is linear at constant

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The correct Answer is:
To analyze the correctness of the statements provided in the question, we will evaluate each option step by step. ### Step 1: Evaluate Option 1 **Statement**: A plot of log Kp versus 1/T is linear. **Explanation**: According to the Arrhenius equation, the rate constant (K) can be expressed as: \[ K = A e^{-\frac{E_a}{RT}} \] Taking the logarithm of both sides gives: \[ \log K = \log A - \frac{E_a}{2.303RT} \] Rearranging this, we can express it as: \[ \log K = \log A - \frac{E_a}{2.303R} \cdot \frac{1}{T} \] This is in the form of \( y = mx + c \), where: - \( y = \log K \) - \( m = -\frac{E_a}{2.303R} \) - \( x = \frac{1}{T} \) Thus, the plot of log Kp versus 1/T is indeed linear. **Conclusion**: Option 1 is correct. ### Step 2: Evaluate Option 2 **Statement**: A plot of log concentration X versus time is linear for a first-order reaction X gives product. **Explanation**: For a first-order reaction, the rate law can be expressed as: \[ Kt = \log \frac{[X_0]}{[X]} \] Rearranging gives: \[ \log [X] = \log [X_0] - Kt \] This can be rewritten as: \[ \log [X] = \log [X_0] - Kt \] This is again in the form of \( y = mx + c \), where: - \( y = \log [X] \) - \( m = -K \) - \( x = t \) Thus, the plot of log concentration X versus time is linear. **Conclusion**: Option 2 is correct. ### Step 3: Evaluate Option 3 **Statement**: A plot of P versus 1/T is linear at constant volume. **Explanation**: According to the ideal gas law, \( PV = nRT \). At constant volume, pressure (P) is directly proportional to temperature (T), which means: \[ P \propto T \] If we express this in terms of 1/T, we find that: \[ P = \text{constant} \cdot T \] This does not yield a linear relationship with respect to 1/T; instead, it results in a hyperbolic relationship. Therefore, the statement is incorrect. **Conclusion**: Option 3 is not correct. ### Step 4: Evaluate Option 4 **Statement**: A plot of P versus 1/V is linear at constant temperature. **Explanation**: At constant temperature, according to Boyle's law, pressure (P) is inversely proportional to volume (V): \[ PV = \text{constant} \] This can be rearranged to: \[ P = \frac{\text{constant}}{V} \] If we plot P versus 1/V, we get a linear relationship because: \[ P = k \cdot \frac{1}{V} \] where k is a constant. Thus, this statement is correct. **Conclusion**: Option 4 is correct. ### Final Conclusion The correct options are 1, 2, and 4.

To analyze the correctness of the statements provided in the question, we will evaluate each option step by step. ### Step 1: Evaluate Option 1 **Statement**: A plot of log Kp versus 1/T is linear. **Explanation**: According to the Arrhenius equation, the rate constant (K) can be expressed as: \[ K = A e^{-\frac{E_a}{RT}} \] Taking the logarithm of both sides gives: ...
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