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A current of 2.68 A is passed for 1.0 ho...

A current of `2.68 A` is passed for `1.0` hour through an aqueous solution of `CuSO_(4)` using copper electrodes.
Which of the following statements is `//` are correct ?

A

Increase in mass of cathode = 3.175 g

B

Decrease in mass of anode = 3.175 g

C

No change in mass of electrodes

D

The ratio between the change in mass of cathode to anode is 1 : 2

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The correct Answer is:
To solve the problem, we need to analyze the electrolysis of copper sulfate (CuSO₄) using copper electrodes and determine the changes in mass at the cathode and anode. ### Step-by-Step Solution: 1. **Determine the total charge passed:** - Current (I) = 2.68 A - Time (t) = 1 hour = 3600 seconds - Total charge (Q) can be calculated using the formula: \[ Q = I \times t = 2.68 \, \text{A} \times 3600 \, \text{s} = 9648 \, \text{C} \] 2. **Calculate the number of Faradays:** - The number of Faradays (F) can be calculated using the formula: \[ F = \frac{Q}{96500} = \frac{9648}{96500} \approx 0.1 \, \text{Faraday} \] 3. **Identify the reactions at the electrodes:** - At the cathode (reduction): \[ \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu (s)} \] - At the anode (oxidation): \[ \text{Cu (s)} \rightarrow \text{Cu}^{2+} + 2e^- \] 4. **Calculate the mass of copper deposited at the cathode:** - From Faraday's laws, 2 Faradays deposit 1 mole of copper (Cu). - Therefore, 0.1 Faraday will deposit: \[ \text{Moles of Cu} = \frac{0.1}{2} = 0.05 \, \text{moles} \] - Mass of copper deposited: \[ \text{Mass} = \text{moles} \times \text{molar mass} = 0.05 \, \text{moles} \times 63.5 \, \text{g/mol} = 3.175 \, \text{g} \] 5. **Calculate the mass of copper dissolved at the anode:** - The same amount of copper that is deposited at the cathode will dissolve at the anode. - Therefore, the mass of copper dissolved at the anode is also: \[ 3.175 \, \text{g} \] 6. **Conclusion:** - The mass of copper deposited at the cathode is 3.175 g. - The mass of copper dissolved at the anode is also 3.175 g. - Hence, the increase in mass at the cathode is equal to the decrease in mass at the anode. ### Correct Statements: 1. The mass of copper deposited at the cathode is 3.175 g (Correct). 2. The mass of copper dissolved at the anode is 3.175 g (Correct). 3. There is a change in mass of the electrodes (Incorrect). ### Summary: - The correct statements are: - The mass of copper deposited at the cathode is 3.175 g. - The mass of copper dissolved at the anode is 3.175 g.

To solve the problem, we need to analyze the electrolysis of copper sulfate (CuSO₄) using copper electrodes and determine the changes in mass at the cathode and anode. ### Step-by-Step Solution: 1. **Determine the total charge passed:** - Current (I) = 2.68 A - Time (t) = 1 hour = 3600 seconds - Total charge (Q) can be calculated using the formula: ...
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